trans-RuH(N₃)[PPh(OEt)2]4

Base Information

Chemical Name:trans-RuH(N₃)[PPh(OEt)2]4
CAS No.:319456-00-3
Molecular Formula:C₄₀H₆₁N₃O₈P₄Ru
Molecular Weight:936.905
Hs Code.:

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Chemical Property of trans-RuH(N₃)[PPh(OEt)2]4

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Technology Process of trans-RuH(N₃)[PPh(OEt)2]4

There total 4 articles about trans-RuH(N₃)[PPh(OEt)2]4 which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 40.0%

: sodium azide

: [RuH(η2-H2)(PPh(OEt)2)4]BF4

: 319456-00-3
trans-RuH(N₃)[PPh(OEt)2]4

Guidance literature:: In ethanol; byproducts: H2; Ru compd. and an excess of NaN3 were treated with ethanol after cooling to -80°C; the mixt. was stirred under an inert atmosphere for 1 h; the vol. of the soln. was reduced by evapn. under reduced pressure; cooling to -25°C; the solid was filtered off and dried under vac.; elem. anal.;
DOI:10.1039/b004833j

Reference yield: 40.0%

: 19597-69-4,157302-05-1
lithium azide

: [RuH(η2-H2)(PPh(OEt)2)4]BF4

: 319456-00-3
trans-RuH(N₃)[PPh(OEt)2]4

Guidance literature:: In ethanol; byproducts: H2; Ru compd. and an excess of LiN3 were treated with ethanol after cooling to -80°C; the mixt. was stirred under an inert atmosphere for 1 h; the vol. of the soln. was reduced by evapn. under reduced pressure; cooling to -25°C; the solid was filtered off and dried under vac.; elem. anal.;
DOI:10.1039/b004833j

Reference yield: 35.0%

: sodium azide

: 123877-52-1,38619-44-2,38720-14-8
RuH₂(PPh(OEt)2)4

: 319456-00-3
trans-RuH(N₃)[PPh(OEt)2]4

Guidance literature:: With CF₃SO₃Me; In ethanol; toluene; byproducts: CH4; to a soln. of Ru compd. in toluene cooled to -80°C CF3SO3Me was added; mixt. was stirred at 0°C under an inert atmosphere for 30 min; excess of NaN3 in EtOH was added; stirring for 1 h; the solvent was removed under reduced pressure; oily residue was treatedwith ethanol; cooling to -25°C; the solid was filtered off and d ried under vac.; elem. anal.;
DOI:10.1039/b004833j