ammonium tetracarbonylcobaltate(-I)

Base Information

Chemical Name:ammonium tetracarbonylcobaltate(-I)
CAS No.:15660-28-3
Molecular Formula:C₄CoO₄*H₄N
Molecular Weight:189.073
Hs Code.:

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of ammonium tetracarbonylcobaltate(-I)

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Technology Process of ammonium tetracarbonylcobaltate(-I)

There total 2 articles about ammonium tetracarbonylcobaltate(-I) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 75.0%

: ammonium hexafluorophosphate

: 113109-24-3
{Pd₂Co₂(CO)7(dppm)2}

: 672-66-2
Dimethyl(phenyl)phosphine

: 15660-28-3
ammonium tetracarbonylcobaltate(-I)

: 113109-41-4
{Pd₂Co(CO)3(dppm)2(PMe₂Ph)}{PF₆}

Guidance literature:: In tetrahydrofuran; PMe2Ph was added dropwise to a soln. of Pd2Co2(CO)7(dppm)2 inTHF. the soln. immediately turned from dark green to intense red and was then stirred with {NH4}{PF6}.; Addn. of n-C6H14; the resulting solid was filtered off, washed (H2O), and dried in vac.; redissolved in THF, the soln. was filtered, and Et2O was added. Further addn. of n-C6H14 and cooling of the soln. resulted in pptn.. Elem.anal.;

Reference yield: 63.0%

: ammonium hexafluorophosphate

: 113109-24-3
{Pd₂Co₂(CO)7(dppm)2}

: 2071-20-7
bis-diphenylphosphinomethane

: 113109-49-2
{Pd₂Co(CO)2(tris{bis(diphenylphosphino)methane})}{PF₆}

: 15660-28-3
ammonium tetracarbonylcobaltate(-I)

Guidance literature:: In tetrahydrofuran; byproducts: CO; The ligand dppm and {NH4}{PF6} were added to a soln. of Pd2Co2(CO)7(dppm)2 in THF and stirred for 1 h.; Solvent removed; residue washed (H2O); dried; purifn. by dissolving in THF, filtering, and pptg. with Et2O/n-hexane (3:1), leaving {NH4}{Co(CO)4} in soln.. Recrystd. of {Pd2Co(CO)2(dppm)3}{PF6} from CH2Cl2/n-hexane. Elem.anal.;