cis-tetracarbonylbis(dichlorophenylphosphine)molybdenum

Base Information

Chemical Name:cis-tetracarbonylbis(dichlorophenylphosphine)molybdenum
CAS No.:22614-54-6
Molecular Formula:C₁₆H₁₀Cl₄MoO₄P₂
Molecular Weight:565.953
Hs Code.:

Synonyms:

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Chemical Property of cis-tetracarbonylbis(dichlorophenylphosphine)molybdenum

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Technology Process of cis-tetracarbonylbis(dichlorophenylphosphine)molybdenum

There total 1 articles about cis-tetracarbonylbis(dichlorophenylphosphine)molybdenum which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 59967-36-1,65337-26-0
cis-tetracarbonylbis(piperidine)molybdenum

: 644-97-3
Dichlorophenylphosphine

: 16244-52-3,22614-54-6
cis-tetracarbonylbis(dichlorophenylphosphine)molybdenum

Guidance literature:: In dichloromethane; the phosphine was added dropwise to Mo-complex in CH2Cl2 with stirring, heated to reflux for 15 min; solvent was removed under reduced pressure, THF was added, stirred for 10 min, filtered, solvent was removed under vac.;
DOI:10.1021/ic025632w

Reference yield: 85.0%

: 16244-52-3,22614-54-6
cis-tetracarbonylbis(dichlorophenylphosphine)molybdenum

: 1643-19-2
tetrabutylammomium bromide

: (nBu₄N){cis-Mo(CO)4(PhPO₂)2H₃}

Guidance literature:: With NaOH; In tetrahydrofuran; byproducts: NaCl, H2O; To a THF-soln. of cis-Mo(CO)4(PhPCl2)2 was added dropwise over 1 h a soln. of 0.44 M NaOH and stirred. The pH was adjusted to ca. 8 and H2O was added and THF removed under vac. and TBABr was added with rigorous stirring and pH was adjusted to 7.; washed with cold water and diethyl ether, elem. anal.;
DOI:10.1021/ja00233a019

Reference yield: 50.0%

: (nBu₄N){cis-Mo(CO)4(PhPO₂)2H₃}

: 16244-52-3,22614-54-6
cis-tetracarbonylbis(dichlorophenylphosphine)molybdenum

: 7646-69-7
sodium hydride

: 117339-95-4
Mo(CO)4(PhPO)4Mo(CO)4

Guidance literature:: In tetrahydrofuran; byproducts: NaCl; To N(butyl)4Mo(CO)4(PhPO2)2H3 in THF was added NaH and stirred until effervescence stopped. cis-Mo(CO)4(PhPCl2)2 in THF was added, after 1 d the ppt. was filtered, extracted with CH2Cl2 and hexane was added to the filtrate.; elem. anal.;
DOI:10.1021/ja00233a019