cis[PtPh₂(1,2-bis(phenylthio)ethane)]

Base Information

• Chemical Name: cis[PtPh₂(1,2-bis(phenylthio)ethane)]
• CAS No.: 105597-80-6
• Molecular Formula: C₂₆H₂₄PtS₂
• Molecular Weight: 595.689
• Mol file: 105597-80-6.mol

Synonyms:

Chemical Property of cis[PtPh₂(1,2-bis(phenylthio)ethane)]

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of cis[PtPh₂(1,2-bis(phenylthio)ethane)]

There total 3 articles about cis[PtPh₂(1,2-bis(phenylthio)ethane)] which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 95.0%

[Pt(Ph)2(Et2S)]2 + 1,2-bis(phenylthio)ethane (622-20-8) → cis[PtPh2(1,2-bis(phenylthio)ethane)] (105597-80-6)

Guidance literature:

In dichloromethane; addn. of stoichiometric amount of the ligand to the soln. of Pt(II) complex; pptn. with Et2O or n-hexane, cooling to -30 ° C, filtration, washing (n-hexane), air drying, elem. anal.;

DOI:10.1002/1099-0682(200203)2002:3<629::AID-EJIC629>3.0.CO;2-J

Reference yield:

cis-diphenylbis(dimethyl sulfoxide)platinum(II) (70423-99-3) → cis[PtPh2(1,2-bis(phenylthio)ethane)] (105597-80-6)

Guidance literature:

Multi-step reaction with 2 steps

1: neat (no solvent)

2: dichloromethane

In dichloromethane;

Reference yield:

cis-diphenylbis(dimethyl sulfoxide)platinum(II) (70423-99-3) + 1,2-bis(phenylthio)ethane (622-20-8) → cis[PtPh2(1,2-bis(phenylthio)ethane)] (105597-80-6)

Guidance literature:

In benzene; byproducts: (CH3)2SO; 303.2K; not isolated; UV (300-400 nm); Kinetics;

upstream raw materials:

cis-diphenylbis(dimethyl sulfoxide)platinum(II)

1,2-bis(phenylthio)ethane

Downstream raw materials:

cis[PtPh₂(1,2-bis(diphenylphosphanyl)propane)]

cis[PtPh₂(1,2-bis(diphenylphosphanyl)methane)]

Refernces

• 1、 Alibrandi, Giuseppe,Bruno, Giuseppe,Lanza, Santo,Minniti, Domenico,Romeo, Raffaello,Tobe, Martin L.. "Dissociative substitution in four-coordinate planar platinum(II) complexes. 2. Crystal structure of cis-diphenylbis(dimethyl sulfide)platinum(II) and kinetics of thioether displacement by bidentate ligands in benzene". . p. 185 - 190. Retrieved 2008/10/08.