Benzoic acid (R)-1-{(E)-2-[(2S,3S,4S)-4-methanesulfonyloxy-6-(2-methoxycarbonyl-ethylsulfanyl)-3-((Z)-6-methoxycarbonyl-hex-2-enyl)-tetrahydro-pyran-2-yl]-vinyl}-hexyl ester

Base Information

Chemical Name:Benzoic acid (R)-1-{(E)-2-[(2S,3S,4S)-4-methanesulfonyloxy-6-(2-methoxycarbonyl-ethylsulfanyl)-3-((Z)-6-methoxycarbonyl-hex-2-enyl)-tetrahydro-pyran-2-yl]-vinyl}-hexyl ester
CAS No.:83641-69-4
Molecular Formula:C₃₃H₄₈O₁₀S₂
Molecular Weight:668.87
Hs Code.:

Benzoic acid (R)-1-{(E)-2-[(2S,3S,4S)-4-methanesulfonyloxy-6-(2-methoxycarbonyl-ethylsulfanyl)-3-((Z)-6-methoxycarbonyl-hex-2-enyl)-tetrahydro-pyran-2-yl]-vinyl}-hexyl ester

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Chemical Property of Benzoic acid (R)-1-{(E)-2-[(2S,3S,4S)-4-methanesulfonyloxy-6-(2-methoxycarbonyl-ethylsulfanyl)-3-((Z)-6-methoxycarbonyl-hex-2-enyl)-tetrahydro-pyran-2-yl]-vinyl}-hexyl ester

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Technology Process of Benzoic acid (R)-1-{(E)-2-[(2S,3S,4S)-4-methanesulfonyloxy-6-(2-methoxycarbonyl-ethylsulfanyl)-3-((Z)-6-methoxycarbonyl-hex-2-enyl)-tetrahydro-pyran-2-yl]-vinyl}-hexyl ester

There total 7 articles about Benzoic acid (R)-1-{(E)-2-[(2S,3S,4S)-4-methanesulfonyloxy-6-(2-methoxycarbonyl-ethylsulfanyl)-3-((Z)-6-methoxycarbonyl-hex-2-enyl)-tetrahydro-pyran-2-yl]-vinyl}-hexyl ester which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 88.0%

: 2935-90-2
Methyl 3-mercaptopropionate

: 83641-68-3
Benzoic acid (R)-1-{(E)-2-[(2S,3S,4S)-6-hydroxy-4-methanesulfonyloxy-3-((Z)-6-methoxycarbonyl-hex-2-enyl)-tetrahydro-pyran-2-yl]-vinyl}-hexyl ester

: 83641-69-4,83641-73-0
Benzoic acid (R)-1-{(E)-2-[(2S,3S,4S)-4-methanesulfonyloxy-6-(2-methoxycarbonyl-ethylsulfanyl)-3-((Z)-6-methoxycarbonyl-hex-2-enyl)-tetrahydro-pyran-2-yl]-vinyl}-hexyl ester

Guidance literature:: With boron trifluoride diethyl etherate; In dichloromethane; at 0 ℃; for 0.25h;
DOI:10.1016/S0040-4039(00)88439-7

Reference yield:

: 62158-43-4,62210-94-0,62211-02-3,65027-25-0,83680-29-9
(Z)-7-[(2S,3R,4R)-4-Hydroxy-2-((E)-(R)-3-hydroxy-oct-1-enyl)-6-methoxy-tetrahydro-pyran-3-yl]-hept-5-enoic acid methyl ester

: 83641-69-4,83641-73-0
Benzoic acid (R)-1-{(E)-2-[(2S,3S,4S)-4-methanesulfonyloxy-6-(2-methoxycarbonyl-ethylsulfanyl)-3-((Z)-6-methoxycarbonyl-hex-2-enyl)-tetrahydro-pyran-2-yl]-vinyl}-hexyl ester

Guidance literature:: Multi-step reaction with 6 steps

1: 90 percent / pyridine / 1 h / -25 °C

2: triphenylphosphine, diethyl azodicarboxylate / tetrahydrofuran / 2 h / 0 °C

3: potassium bicarbonate / methanol / 0.5 h / 25 °C

4: 98 percent / triethylamine / 0.17 h / -25 °C

5: 67 percent / acetic acid, THF, H₂O, phosphoric acid / 4 h / 55 °C

6: 88 percent / boron trifluoride etherate / CH₂Cl₂ / 0.25 h / 0 °C

With tetrahydrofuran; pyridine; phosphoric acid; boron trifluoride diethyl etherate; water; potassium hydrogencarbonate; acetic acid; triethylamine; triphenylphosphine; diethylazodicarboxylate; In tetrahydrofuran; methanol; dichloromethane;
DOI:10.1016/S0040-4039(00)88439-7

Reference yield:

: Benzoic acid (R)-1-{(E)-2-[(2S,3R,4S)-4-formyloxy-6-methoxy-3-((Z)-6-methoxycarbonyl-hex-2-enyl)-tetrahydro-pyran-2-yl]-vinyl}-hexyl ester

: 83641-69-4,83641-73-0
Benzoic acid (R)-1-{(E)-2-[(2S,3S,4S)-4-methanesulfonyloxy-6-(2-methoxycarbonyl-ethylsulfanyl)-3-((Z)-6-methoxycarbonyl-hex-2-enyl)-tetrahydro-pyran-2-yl]-vinyl}-hexyl ester

Guidance literature:: Multi-step reaction with 4 steps

1: potassium bicarbonate / methanol / 0.5 h / 25 °C

2: 98 percent / triethylamine / 0.17 h / -25 °C

3: 67 percent / acetic acid, THF, H₂O, phosphoric acid / 4 h / 55 °C

4: 88 percent / boron trifluoride etherate / CH₂Cl₂ / 0.25 h / 0 °C

With tetrahydrofuran; phosphoric acid; boron trifluoride diethyl etherate; water; potassium hydrogencarbonate; acetic acid; triethylamine; In methanol; dichloromethane;
DOI:10.1016/S0040-4039(00)88439-7