((C₆H₅)2PC₆H₄CHPC₆H₂(C(CH₃)3)3)PdCl₂

Base Information

• Chemical Name: ((C₆H₅)2PC₆H₄CHPC₆H₂(C(CH₃)3)3)PdCl₂
• CAS No.: 351208-32-7
• Molecular Formula: C₃₇H₄₄Cl₂P₂Pd
• Molecular Weight: 728.03
• Mol file: 351208-32-7.mol

Synonyms:

Chemical Property of ((C₆H₅)2PC₆H₄CHPC₆H₂(C(CH₃)3)3)PdCl₂

Chemical Property:

Purity/Quality:

Safty Information:

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MSDS Files:

Useful:

Technology Process of ((C₆H₅)2PC₆H₄CHPC₆H₂(C(CH₃)3)3)PdCl₂

There total 2 articles about ((C₆H₅)2PC₆H₄CHPC₆H₂(C(CH₃)3)3)PdCl₂ which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 85.0%

palladium dichloride + 1,3,5-Tri-tert-butyl-2-{[1-(2-diphenylphosphanyl-phenyl)-meth-(E)-ylidene]-phosphanyl}-benzene → ((C6H5)2PC6H4CHPC6H2(C(CH3)3)3)PdCl2 (351208-32-7)

Guidance literature:

In methanol; susp. of PdCl2 in MeOH added to an equimolar amt. of the ligand with stirring at ambient temp.; after 3 d, yellow ppt. filtered off, washed with hot EtOH and dried in vacuo; identified by elem. anal.;

DOI:10.1016/S0022-328X(01)00654-4

Reference yield:

potassium tetrachloropalladate(II) + 1,3,5-Tri-tert-butyl-2-{[1-(2-diphenylphosphanyl-phenyl)-meth-(E)-ylidene]-phosphanyl}-benzene → ((C6H5)2PC6H4CHPC6H2(C(CH3)3)3)PdCl2 (351208-32-7)

Guidance literature:

In methanol; susp. of K2PdCl4 in MeOH added to an equimolar amt. of the ligand with stirring at ambient temp.; after 3 d, yellow ppt. filtered off, washed with hot EtOH and dried in vacuo; identified by elem. anal.;

DOI:10.1016/S0022-328X(01)00654-4