cis-bis(2-methylphenylphosphanyl-4-methylphenolato)nickel

Base Information

Chemical Name:cis-bis(2-methylphenylphosphanyl-4-methylphenolato)nickel
CAS No.:260251-75-0
Molecular Formula:C₂₈H₂₈NiO₂P₂
Molecular Weight:517.167
Hs Code.:

Synonyms:

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Chemical Property of cis-bis(2-methylphenylphosphanyl-4-methylphenolato)nickel

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Technology Process of cis-bis(2-methylphenylphosphanyl-4-methylphenolato)nickel

There total 3 articles about cis-bis(2-methylphenylphosphanyl-4-methylphenolato)nickel which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 59.0%

: 6018-89-9
nickel(II) acetate tetrahydrate

: 185509-25-5
2-methylphenylphosphanyl-4-methylphenol

: 260251-75-0
cis-bis(2-methylphenylphosphanyl-4-methylphenolato)nickel

Guidance literature:: In ethanol; under Ar, Schlenk techniques; soln. of ligand in EtOH was added to warm soln. of Ni(OAc)2*4H2O in EtOH; solvent was removed in vacuo after 3 d, residue extracted with CH2Cl2, extract soln. dried with Na2SO4, hexane was added, part of the solvent was evapd. in vacuo, ppt. was sepd. and dried for 2 h at 1E-2 Torr; elem. anal.;
DOI:10.1002/(sici)1099-0682(200002)2000:2<299::aid-ejic299>3.0.co;2-j

Reference yield: 34.0%

: 3264-82-2
nickel(II) acetylacetonate

: Methyl-(5-methyl-2-trimethylsilanyloxy-phenyl)-phenyl-phosphane

: 260251-75-0
cis-bis(2-methylphenylphosphanyl-4-methylphenolato)nickel

Guidance literature:: In benzene; under Ar, Schlenk techniques; mixt. of ligand and Ni-complex was refluxed for 8 h in benzene; part of the solvent was removed;
DOI:10.1002/(sici)1099-0682(200002)2000:2<299::aid-ejic299>3.0.co;2-j

Reference yield:

: 252570-21-1
cyclopentadienyl(2-isopropylphenylphosphanyl-4-methylphenolato)nickel

: 185509-25-5
2-methylphenylphosphanyl-4-methylphenol

: 260251-75-0
cis-bis(2-methylphenylphosphanyl-4-methylphenolato)nickel

: 260251-76-1
Ni(C₆H₃CH₃OP(C₆H₅))2C₃H₇CH₃

: 193072-78-5
cis-bis(2-isopropylphenylphosphanyl-4-methylphenolato)nickel

Guidance literature:: In benzene; soln. of Ni-complex in benzene was added to soln. of ligand in benzene under Ar; solvent was distilled, ppt. was sepd.; detected by NMR;
DOI:10.1002/(sici)1099-0682(200002)2000:2<299::aid-ejic299>3.0.co;2-j