BENZYL-VINYL CARBONATE

Base Information

• Chemical Name: BENZYL-VINYL CARBONATE
• CAS No.: 113150-67-7
• Molecular Formula: C10H10O3
• Molecular Weight: 178.188
• Mol file: 113150-67-7.mol

Synonyms:BENZYL-VINYL CARBONATE;benzylvinyl carbonate;

Chemical Property of BENZYL-VINYL CARBONATE

Chemical Property:

• Boiling Point: 112-115 °C(Press: 4 Torr)
• PSA: 35.53000
• Density: 1.112±0.06 g/cm3(Predicted)
• LogP: 2.48330

Purity/Quality:

99% ^*data from raw suppliers

BenzylVinylCarbonate ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Uses: Benzyl Vinyl Carbonate can be used in the synthesis of immunosuppressive compounds, in addition to reagents in the synthesis of varying carbonates.

Technology Process of BENZYL-VINYL CARBONATE

There total 2 articles about BENZYL-VINYL CARBONATE which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 89.0%

Benzyl Fluoroformate (93942-41-7) + acetaldehyde (75-07-0,9002-91-9) → benzyl vinyl carbonate (113150-67-7)

Guidance literature:

With potassium fluoride; 18-crown-6 ether; In acetonitrile; at 70 ℃; for 3.5h;

DOI:10.1021/jo00288a001

Reference yield: 75.0%

Vinyl chloroformate (5130-24-5) + benzyl alcohol (100-51-6,185532-71-2) → benzyl vinyl carbonate (113150-67-7)

Guidance literature:

With pyridine; for 0.5h;

DOI:10.1016/S0040-4020(01)88237-5

Reference yield: 99.0%

2-(benzyloxycarbonyl)amino-2-[2-(4-octylphenyl)ethyl]propane-1,3-diol (402616-41-5) + benzyl vinyl carbonate (113150-67-7) → (R)-2-(benzyloxycarbonyl)amino-2-(benzyloxycarbonyloxy)methyl-4-(4-octylphenyl)butanol

Guidance literature:

With immobilized lipase; In tetrahydrofuran; at 20 ℃; for 16h;

DOI:10.1016/j.bmc.2004.10.008

upstream raw materials:

Benzyl Fluoroformate

acetaldehyde

Vinyl chloroformate

benzyl alcohol

Downstream raw materials:

DBC

carbonic acid benzyl ester octyl ester

benzyl-1-(2-ethyl)-hexyl carbonate

R-(-)-benzyl-2-octyl carbonate