(η5-cyclopentadienide)2Ti((3-dimethylphosphino)propane-1-thiolate-κ2S,P) tetrafluoroborate*acetonitrile

Base Information

Chemical Name:(η5-cyclopentadienide)2Ti((3-dimethylphosphino)propane-1-thiolate-κ2S,P) tetrafluoroborate*acetonitrile
CAS No.:604802-79-1
Molecular Formula:C₁₅H₂₂PSTi*C₂₄H₂₀B
Molecular Weight:632.493
Hs Code.:

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of (η5-cyclopentadienide)2Ti((3-dimethylphosphino)propane-1-thiolate-κ2S,P) tetrafluoroborate*acetonitrile

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Technology Process of (η5-cyclopentadienide)2Ti((3-dimethylphosphino)propane-1-thiolate-κ2S,P) tetrafluoroborate*acetonitrile

There total 1 articles about (η5-cyclopentadienide)2Ti((3-dimethylphosphino)propane-1-thiolate-κ2S,P) tetrafluoroborate*acetonitrile which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 82.0%

: 1271-19-8
bis(cyclopentadienyl)titanium dichloride

: 604802-90-6
lithium (2-dimethylphosphino)propane-1-thiolate

: 143-66-8
sodium tetraphenyl borate

: 604802-79-1
(η5-cyclopentadienide)2Ti((3-dimethylphosphino)propane-1-thiolate-κ2S,P) tetrafluoroborate*acetonitrile

Guidance literature:: In tetrahydrofuran; Ar; addn. of 1 equiv. of Li compd. in THF to THF soln. of Ti complex at 0°C, stirring for 2 h at room temp., solvent evapn., extn. with toluene, evapn., dissolving in THF, addn. of NaB(C6H5)4 in THF, stirring overnight; THF removal, recrystn. from CH3CN/diethyl ether; elem. anal.;
DOI:10.1021/ic034353l