trans-PdMePh(PEt₂Ph)2

Base Information

• Chemical Name: trans-PdMePh(PEt₂Ph)2
• CAS No.: 113566-59-9
• Molecular Formula: C₂₇H₃₈P₂Pd
• Molecular Weight: 530.966
• Mol file: 113566-59-9.mol

Synonyms:

Chemical Property of trans-PdMePh(PEt₂Ph)2

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of trans-PdMePh(PEt₂Ph)2

There total 2 articles about trans-PdMePh(PEt₂Ph)2 which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 41.0%

trans-PdPh(Br)(PEt2Ph)2 (115680-90-5) → trans-PdMePh(PEt2Ph)2 (113566-59-9) + cis-PdMePh(PEt2Ph)2 (113530-48-6)

Guidance literature:

With methyllithium; In diethyl ether; byproducts: LiBr; under Ar, N2 or vac.; addn. of Et2O soln. of MeLi to heterogeneous mixt. of trans-PdPh(Br)(PEt2Ph)2 and Et2O contg. styrene at -70°C; stirred at -10 to 0°C, 2h; addn. of dioxane at -30°C (pptn. of LiBr); filtered at -40°C; concn.; addn. of hexane at -70°C; pptn.; recrystn. (Et2O; some styrene; <-10°C to remove cis-PdMePh(PEt2Ph)2); pptn.; elem. anal.;

DOI:10.1021/om00103a023

Reference yield:

Al(CH3)(OC2H5)(C6H5) + palladium(II) acetylacetonate + diethyl-phenyl-phosphine (1605-53-4) → trans-PdMePh(PEt2Ph)2 (113566-59-9)

Guidance literature:

In diethyl ether;

Reference yield:

trans-PdMePh(PEt2Ph)2 (113566-59-9) → trans-PdPh(I)(PEt2Ph)2 (113530-53-3)

Guidance literature:

With iodobenzene; In benzene; byproducts: toluene; under Ar; N2 or vac.; in benzene at 45°C;

DOI:10.1021/om00103a023

upstream raw materials:

diethyl-phenyl-phosphine

trans-PdPh(Br)(PEt₂Ph)2

Downstream raw materials:

trans-PdPh(I)(PEt₂Ph)2