[2-(diphenylphosphino)ethyl]ferrocene

Base Information

Chemical Name:[2-(diphenylphosphino)ethyl]ferrocene
CAS No.:803739-86-8
Molecular Formula:C₂₄H₂₃FeP
Molecular Weight:398.267
Hs Code.:

Synonyms:

Suppliers and Price of [2-(diphenylphosphino)ethyl]ferrocene

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 0 raw suppliers

Chemical Property of [2-(diphenylphosphino)ethyl]ferrocene

Chemical Property:

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Technology Process of [2-(diphenylphosphino)ethyl]ferrocene

There total 1 articles about [2-(diphenylphosphino)ethyl]ferrocene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 71.0%

: 2‐bromoethylferrocene

: 7439-95-4
magnesium

: 1079-66-9,74391-44-9
chloro-diphenylphosphine

: 803739-86-8
[2-(diphenylphosphino)ethyl]ferrocene

Guidance literature:: In tetrahydrofuran; (Ar or N2); using Schlenk techniques; treatment of Mg with FcCH2CH2Br inTHF; addn. dropwise of THF soln. of Ph2PCl at 0°C; stirring for 3 h at room temp.; evapn. of volatiles to dryness under reduced pressure, extn. with benzene, chromy. over silica gel (elution with hexane/benzene =3/1) under N2;
DOI:10.1016/j.ica.2004.05.019

Reference yield: 48.0%

: ammonium hexafluorophosphate

: 803739-86-8
[2-(diphenylphosphino)ethyl]ferrocene

: 108-67-8
1,3,5-trimethyl-benzene

: (1,3,5-trimethyl-η6-benzene)(η5-cyclopentadienyl)iron(II) hexafluorophosphate

: 803739-88-0
(η6-mesitylene) [η5-(2-(diphenylphosphino)ethyl)cyclopentadienyl]iron(II) hexafluorophosphate

Guidance literature:: With Al; AlCl₃; In cyclohexane; water; (Ar or N2); using Schlenk techniques; reflux of AlCl3, Al, FcCH2CH2PPh2,mesitylene and water in cyclohexane for 5 h; cooling to 0°C; que nching with cold H2O; sepn. of aq. layer, filtration, washing with ether, addn. of excess NH4PF6 soln.; filtration, washing with cold water, drying, washing with ether, recrystn. from CH2Cl2/ether; as inseparable mixt.;
DOI:10.1016/j.ica.2004.05.019