benzyl diacetoxysuccinic acid

Base Information

• Chemical Name: benzyl diacetoxysuccinic acid
• CAS No.: 123524-99-2
• Molecular Formula: C₁₅H₁₆O₈
• Molecular Weight: 324.287
• Mol file: 123524-99-2.mol

Synonyms:

Chemical Property of benzyl diacetoxysuccinic acid

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of benzyl diacetoxysuccinic acid

There total 1 articles about benzyl diacetoxysuccinic acid which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 96.0%

(3R-trans)-dihydro-2,5-dioxofuran-3,4-diyl diacetate (6283-74-5) + benzyl alcohol (100-51-6,185532-71-2) → benzyl diacetoxysuccinic acid (123524-99-2)

Guidance literature:

With dmap; Ambient temperature;

DOI:10.1016/S0040-4020(01)80133-2

Reference yield:

benzyl diacetoxysuccinic acid (123524-99-2) → 4-t-butyl O-benzyl diacetoxysuccinohydroxamate (112233-48-4)

Guidance literature:

Multi-step reaction with 3 steps

1: 62 percent / 70percent perchloric acid / 24 h / Ambient temperature

2: H₂ / 10percent Pd-C / ethyl acetate

3: 1.) N-hydroxy succinimide, DCC, 2.) NaHCO₃ / 1.) ethyl acetate, 0 grad C to room temp., 4 h, 2.) H₂O

With 1-hydroxy-pyrrolidine-2,5-dione; perchloric acid; hydrogen; sodium hydrogencarbonate; dicyclohexyl-carbodiimide; palladium on activated charcoal; In ethyl acetate;

DOI:10.1016/S0040-4020(01)80133-2

upstream raw materials:

(3R-trans)-dihydro-2,5-dioxofuran-3,4-diyl diacetate

benzyl alcohol

Downstream raw materials:

4-t-butyl O-benzyl diacetoxysuccinohydroxamate