[Ir2(Me)(CO)(μ-η1:η3-H2CCCH2)(bis(diphenylphosphino)methane)2](CF3SO3)

Base Information

Chemical Name:[Ir2(Me)(CO)(μ-η1:η3-H2CCCH2)(bis(diphenylphosphino)methane)2](CF3SO3)
CAS No.:862604-92-0
Molecular Formula:CF₃O₃S*C₅₆H₅₁Ir₂O₂P₄
Molecular Weight:1413.43
Hs Code.:

Synonyms:

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Chemical Property of [Ir2(Me)(CO)(μ-η1:η3-H2CCCH2)(bis(diphenylphosphino)methane)2](CF3SO3)

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Technology Process of [Ir2(Me)(CO)(μ-η1:η3-H2CCCH2)(bis(diphenylphosphino)methane)2](CF3SO3)

There total 2 articles about [Ir2(Me)(CO)(μ-η1:η3-H2CCCH2)(bis(diphenylphosphino)methane)2](CF3SO3) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 73.0%

: 206441-50-1
[Ir2(CH3)(CO)(μ-CO)(dppm)2](CF3SO3)

: 463-49-0
1,2-propanediene

: 206441-60-3,862604-92-0
[Ir2(Me)(CO)(μ-η1:η3-H2CCCH2)(bis(diphenylphosphino)methane)2](CF3SO3)

Guidance literature:: In dichloromethane; (Ar); using Schlenk techniques; cooling of soln. of Ir2(CO)2(Me)(dppm)2(CF3SO3) at -78°C; passing of allene through soln. for 1 min; stirring at -78°C for 30 min; warming to room temp.; stirring for 1 h; concn., addn. of Et2O, pptn., washing with Et2O, drying under vac., elem. anal.;
DOI:10.1021/om0580102

Reference yield:

: [Ir2H(CO)2(η2-H2CCCH2)(μ-CH2)(bis(diphenylphosphino)methane)2](CF3SO3)

: 862604-97-5,206441-62-5
[Ir2(Me)(CO)(μ-η1:η3-H2CCCH2)(bis(diphenylphosphino)methane)2(CF3SO3)

: 206441-60-3,862604-92-0
[Ir2(Me)(CO)(μ-η1:η3-H2CCCH2)(bis(diphenylphosphino)methane)2](CF3SO3)

Guidance literature:: In dichloromethane-d2; (Ar); using Schlenk techniques; addn. of methylallene to mixt. syn- and anti-Ir2H(CO)2(η2-H2CCCH2)(μ-CH2)(dppm)2(CF3SO3) in CD2Cl2 at -78°C; slow warming; further intermediate; leaving at ambient temp. for several hours; monitoring by NMR;
DOI:10.1021/om0580102

Reference yield: 80.0%

: 206441-60-3,862604-92-0
[Ir2(Me)(CO)(μ-η1:η3-H2CCCH2)(bis(diphenylphosphino)methane)2](CF3SO3)

: [Ir2H(CO)2(μ-eta.(1),η(3)-CHC(CH3)CH2)(dppm)2](CF3SO3)

Guidance literature:: In dichloromethane; (Ar); using Schlenk techniques; dissolving of Ir2(CO)2(Me)(μ-η1:η3-H2CCCH2)(dppm)2(CF3SO3) in CH2Cl2; stirring for 7 days; concn., addn. of Et2O, pptn., washing with Et2O, drying under vac.;
DOI:10.1021/om0580102