trans-4,4-diethoxy-1,2-bis(hydroxymethyl)cyclohexane bis(toluenesulfonate)

Base Information

Chemical Name:trans-4,4-diethoxy-1,2-bis(hydroxymethyl)cyclohexane bis(toluenesulfonate)
CAS No.:113251-40-4
Molecular Formula:C₂₆H₃₆O₈S₂
Molecular Weight:540.699
Hs Code.:

Synonyms:

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of trans-4,4-diethoxy-1,2-bis(hydroxymethyl)cyclohexane bis(toluenesulfonate)

Chemical Property:

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Technology Process of trans-4,4-diethoxy-1,2-bis(hydroxymethyl)cyclohexane bis(toluenesulfonate)

There total 2 articles about trans-4,4-diethoxy-1,2-bis(hydroxymethyl)cyclohexane bis(toluenesulfonate) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 113251-38-0
diethyl trans-4-oxocyclohexane-1,2-dicarboxylate

: 113251-40-4
trans-4,4-diethoxy-1,2-bis(hydroxymethyl)cyclohexane bis(toluenesulfonate)

Guidance literature:: Multi-step reaction with 3 steps

1: 83 percent / p-TsOH / ethanol / 18 h / 20 °C

2: 82 percent / LiAlH₄ / tetrahydrofuran / 24 h / Heating

3: 88 percent / pyridine / 1.) 0 deg C, 2 h, 2.) 4 deg C, 1 d

With pyridine; lithium aluminium tetrahydride; toluene-4-sulfonic acid; In tetrahydrofuran; ethanol;
DOI:10.1021/jo00243a004

Reference yield:

: diethyl trans-4,4-diethoxycyclohexane-1,2-dicarboxylate

: 113251-40-4
trans-4,4-diethoxy-1,2-bis(hydroxymethyl)cyclohexane bis(toluenesulfonate)

Guidance literature:: Multi-step reaction with 2 steps

1: 82 percent / LiAlH₄ / tetrahydrofuran / 24 h / Heating

2: 88 percent / pyridine / 1.) 0 deg C, 2 h, 2.) 4 deg C, 1 d

With pyridine; lithium aluminium tetrahydride; In tetrahydrofuran;
DOI:10.1021/jo00243a004

Reference yield:

: 113251-40-4
trans-4,4-diethoxy-1,2-bis(hydroxymethyl)cyclohexane bis(toluenesulfonate)

: 69308-17-4
trans-3,4-dimethylcyclohexan-1α-ol

Guidance literature:: Multi-step reaction with 4 steps

1: Na₂S / ethanol; H₂O / 4 h / Heating

2: 2 M HCl / ethanol; H₂O / 1.5 h / 20 °C

3: 33 percent / 0.1 M phosphate buffer / 120 h / 20 °C / horse liver alcohol dehydrogenase (HLADH), pH 7

4: 63 percent / Raney Ni, MeOH / 0.33 h / Heating

With hydrogenchloride; methanol; sodium sulfide; phosphate buffer; nickel; In ethanol; water;
DOI:10.1021/jo00243a004