Technology Process of Stannane, tributyl-1-octynyl-
There total 3 articles about Stannane, tributyl-1-octynyl- which
guide to synthetic route it.
The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:
synthetic route:
- Guidance literature:
-
With
pyridine; 2,2,6,6-Tetramethyl-1-piperidinyloxy free radical; zinc trifluoromethanesulfonate;
at 70 ℃;
for 8h;
chemoselective reaction;
Schlenk technique;
Inert atmosphere;
DOI:10.1002/adsc.201900540
- Guidance literature:
-
With
zinc dibromide;
In
tetrahydrofuran;
at 20 ℃;
for 3h;
Inert atmosphere;
DOI:10.1246/cl.140888
- Guidance literature:
-
With
n-butyllithium;
In
tetrahydrofuran;
byproducts: LiCl; a soln. of oct-1-yne in THF is cooled to -78°C and BuLi is slowly added with stirring, mixt. is stirred for 1 h, Bu3SnCl in THF is then added, mixt. is allowed to reach room temp. and stirred for a further hour; filtn. from LiCl;
