Technology Process of Stannane, tributyl-1-octynyl-
There total 3 articles about Stannane, tributyl-1-octynyl- which
guide to synthetic route it.
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synthetic route:
- Guidance literature:
-
With
pyridine; 2,2,6,6-Tetramethyl-1-piperidinyloxy free radical; zinc trifluoromethanesulfonate;
at 70 ℃;
for 8h;
chemoselective reaction;
Schlenk technique;
Inert atmosphere;
DOI:10.1002/adsc.201900540
- Guidance literature:
-
With
zinc dibromide;
In
tetrahydrofuran;
at 20 ℃;
for 3h;
Inert atmosphere;
DOI:10.1246/cl.140888
- Guidance literature:
-
With
n-butyllithium;
In
tetrahydrofuran;
byproducts: LiCl; a soln. of oct-1-yne in THF is cooled to -78°C and BuLi is slowly added with stirring, mixt. is stirred for 1 h, Bu3SnCl in THF is then added, mixt. is allowed to reach room temp. and stirred for a further hour; filtn. from LiCl;