ovalicin

Base Information

• Chemical Name: ovalicin
• CAS No.: 137490-44-9
• Molecular Formula: C₁₆H₂₄O₅
• Molecular Weight: 296.364
• Mol file: 137490-44-9.mol

Synonyms:

Chemical Property of ovalicin

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of ovalicin

There total 40 articles about ovalicin which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 78.0%

FOS-34 (214688-36-5) → (-)-ovalicin (19683-98-8,94233-47-3,137490-44-9)

Guidance literature:

With dipyridinium dichromate; In dichloromethane;

DOI:10.1039/c39940001495

Reference yield: 71.0%

(3S,4R,5S)-4-((E)-1',5'-dimethylhexa-1',4'-dienyl)-4-hydroxy-5-methoxy-1-oxaspiro[2,5]octan-6-one (870862-62-7) → (-)-ovalicin (19683-98-8,94233-47-3,137490-44-9)

Guidance literature:

With tert.-butylhydroperoxide; vanadyl acetylacetonate; In benzene; for 1.5h;

DOI:10.1002/anie.200604781

Reference yield: 48.0%

C16H24O4 → (-)-ovalicin (19683-98-8,94233-47-3,137490-44-9)

Guidance literature:

With tert.-butylhydroperoxide; bis(acetylacetonate)oxovanadium; In toluene; at 0 ℃;

DOI:10.1055/s-0029-1219191

upstream raw materials:

FOS-34

(3S,4R,5S)-4-((E)-1',5'-dimethylhexa-1',4'-dienyl)-4-hydroxy-5-methoxy-1-oxaspiro[2,5]octan-6-one

(R)-4-hydroxy-1,4-dioxa-spiro[4.5]decan-8-one

(3S,4R)-1,7,10-Trioxa-dispiro[2.2.4.2]dodecan-4-ol