Re2Cl3(C(CN)3)(μ-dppm)2(CO)(CNXyl)

Base Information

• Chemical Name: Re2Cl3(C(CN)3)(μ-dppm)2(CO)(CNXyl)
• CAS No.: 374596-51-7
• Molecular Formula: C₆₄H₅₃Cl₃N₄OP₄Re₂
• Molecular Weight: 1496.82
• Mol file: 374596-51-7.mol

Synonyms:

Chemical Property of Re2Cl3(C(CN)3)(μ-dppm)2(CO)(CNXyl)

Chemical Property:

Purity/Quality:

Safty Information:

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MSDS Files:

Useful:

Technology Process of Re2Cl3(C(CN)3)(μ-dppm)2(CO)(CNXyl)

There total 1 articles about Re2Cl3(C(CN)3)(μ-dppm)2(CO)(CNXyl) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 75.0%

Re2(μ-Cl)(μ-CO)Cl3(CNC6H3Me2)(μ-Ph2PCH2PPh2)2 + sodium tricyanomethanide (36603-80-2) → Re2Cl3(C(CN)3)(μ-dppm)2(CO)(CNXyl) (374596-51-7)

Guidance literature:

In methanol; dichloromethane; soln. Na(C(CN)3) in MeOH was added to soln. dirhenium complex in CH2Cl2 and refluxed for 18 h; soln. was filtered and concd., Et2O was added, ppt. was washed with MeOHand Et2O and crystd. from diisopropyl ether/1,2-dichloroethane/benzene; elem. anal.;

DOI:10.1021/ic010442r

Reference yield:

Re2Cl3(C(CN)3)(μ-dppm)2(CO)(CNXyl) (374596-51-7) + 1,2-dichloro-ethane (107-06-2,52399-93-6) → Re2Cl3(C(CN)3)(μ-dppm)2(CO)(CNXyl)*0.436C2H4Cl2

Guidance literature:

In di-isopropyl ether; 1,2-dichloro-ethane; diffusion diisopropyl ether to soln. in 1,2-dichloroethane/1,2-dichlorobenzene;

DOI:10.1021/ic010442r

upstream raw materials:

sodium tricyanomethanide

Refernces