6-O-(benzyloxycarbonyl)-2-<(3S)-3-(benzyloxy)tetradecanamido>-2-deoxy-3-O-<(3R)-3-(tetradecanoyloxy)tetradecanoyl>-α(/β)-D-glucopyranosyl fluoride 4-(diphenyl phosphate)

Base Information

Chemical Name:6-O-(benzyloxycarbonyl)-2-<(3S)-3-(benzyloxy)tetradecanamido>-2-deoxy-3-O-<(3R)-3-(tetradecanoyloxy)tetradecanoyl>-α(/β)-D-glucopyranosyl fluoride 4-(diphenyl phosphate)
CAS No.:138527-62-5
Molecular Formula:C₇₅H₁₁₁FNO₁₄P
Molecular Weight:1300.68
Hs Code.:

6-O-(benzyloxycarbonyl)-2-<(3S)-3-(benzyloxy)tetradecanamido>-2-deoxy-3-O-<(3R)-3-(tetradecanoyloxy)tetradecanoyl>-α(/β)-D-glucopyranosyl fluoride 4-(diphenyl phosphate)

Synonyms:

Suppliers and Price of 6-O-(benzyloxycarbonyl)-2-<(3S)-3-(benzyloxy)tetradecanamido>-2-deoxy-3-O-<(3R)-3-(tetradecanoyloxy)tetradecanoyl>-α(/β)-D-glucopyranosyl fluoride 4-(diphenyl phosphate)

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 0 raw suppliers

Chemical Property of 6-O-(benzyloxycarbonyl)-2-<(3S)-3-(benzyloxy)tetradecanamido>-2-deoxy-3-O-<(3R)-3-(tetradecanoyloxy)tetradecanoyl>-α(/β)-D-glucopyranosyl fluoride 4-(diphenyl phosphate)

Chemical Property:

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Technology Process of 6-O-(benzyloxycarbonyl)-2-<(3S)-3-(benzyloxy)tetradecanamido>-2-deoxy-3-O-<(3R)-3-(tetradecanoyloxy)tetradecanoyl>-α(/β)-D-glucopyranosyl fluoride 4-(diphenyl phosphate)

There total 10 articles about 6-O-(benzyloxycarbonyl)-2-<(3S)-3-(benzyloxy)tetradecanamido>-2-deoxy-3-O-<(3R)-3-(tetradecanoyloxy)tetradecanoyl>-α(/β)-D-glucopyranosyl fluoride 4-(diphenyl phosphate) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 87357-76-4
(R)-3-(dodecanoyloxy)tetradecanoic acid

: 138527-62-5,138527-65-8,138540-35-9,139616-87-8
6-O-(benzyloxycarbonyl)-2-<(3S)-3-(benzyloxy)tetradecanamido>-2-deoxy-3-O-<(3R)-3-(tetradecanoyloxy)tetradecanoyl>-α(/β)-D-glucopyranosyl fluoride 4-(diphenyl phosphate)

Guidance literature:: Multi-step reaction with 6 steps

1: 73 percent / N,N-dicyclohexylcarbodiimide, DMPA / tetrahydrofuran / 4 h

2: 69 percent / 90percent aq. AcOH / 0.83 h / 60 °C

3: 65 percent / DMAP / CH₂Cl₂ / 3 h / Ambient temperature

4: 95 percent / DMAP / CH₂Cl₂ / 1 h / Ambient temperature

5: 2) H₂O, pyridine, I₂ / 1) 8H₁₂Ir(PMePh₂)2>PF₆ / THF, 1) 3h, r.t., 2) 30 min

6: diethylaminosulfur trifluoride / CH₂Cl₂ / 1) 1h, 0 deg C, 2) 30 min, r.t.

With pyridine; dmap; diethylamino-sulfur trifluoride; 0,2,4-dichlorophenyl-0-methylisopropylamidothiophosphate; water; iodine; acetic acid; dicyclohexyl-carbodiimide; PF6; In tetrahydrofuran; dichloromethane;
DOI:10.1016/0008-6215(91)89008-4

Reference yield:

: 138527-55-6
allyl 2-amino-2-deoxy-4,6-O-isopropylidene-α-D-glucopyranoside

: 138527-62-5,138527-65-8,138540-35-9,139616-87-8
6-O-(benzyloxycarbonyl)-2-<(3S)-3-(benzyloxy)tetradecanamido>-2-deoxy-3-O-<(3R)-3-(tetradecanoyloxy)tetradecanoyl>-α(/β)-D-glucopyranosyl fluoride 4-(diphenyl phosphate)

Guidance literature:: Multi-step reaction with 7 steps

1: 35 percent / N,N-dicyclohexylcarbodiimide / CH₂Cl₂ / 1 h / 25 °C

2: 73 percent / N,N-dicyclohexylcarbodiimide, DMPA / tetrahydrofuran / 4 h

3: 69 percent / 90percent aq. AcOH / 0.83 h / 60 °C

4: 65 percent / DMAP / CH₂Cl₂ / 3 h / Ambient temperature

5: 95 percent / DMAP / CH₂Cl₂ / 1 h / Ambient temperature

6: 2) H₂O, pyridine, I₂ / 1) 8H₁₂Ir(PMePh₂)2>PF₆ / THF, 1) 3h, r.t., 2) 30 min

7: diethylaminosulfur trifluoride / CH₂Cl₂ / 1) 1h, 0 deg C, 2) 30 min, r.t.

With pyridine; dmap; diethylamino-sulfur trifluoride; 0,2,4-dichlorophenyl-0-methylisopropylamidothiophosphate; water; iodine; acetic acid; dicyclohexyl-carbodiimide; PF6; In tetrahydrofuran; dichloromethane;
DOI:10.1016/0008-6215(91)89008-4

Reference yield:

: 138527-88-5
allyl 6-O-(benzyloxycarbonyl)-2-<(3S)-3-(benzyloxy)tetradecanamido>-2-deoxy-3-O-<(3R)-3-(tetradecanoyloxy)tetradecanoyl>-α-D-glucopyranoside

: 138527-62-5,138527-65-8,138540-35-9,139616-87-8
6-O-(benzyloxycarbonyl)-2-<(3S)-3-(benzyloxy)tetradecanamido>-2-deoxy-3-O-<(3R)-3-(tetradecanoyloxy)tetradecanoyl>-α(/β)-D-glucopyranosyl fluoride 4-(diphenyl phosphate)

Guidance literature:: Multi-step reaction with 3 steps

1: 95 percent / DMAP / CH₂Cl₂ / 1 h / Ambient temperature

2: 2) H₂O, pyridine, I₂ / 1) 8H₁₂Ir(PMePh₂)2>PF₆ / THF, 1) 3h, r.t., 2) 30 min

3: diethylaminosulfur trifluoride / CH₂Cl₂ / 1) 1h, 0 deg C, 2) 30 min, r.t.

With pyridine; dmap; diethylamino-sulfur trifluoride; water; iodine; PF6; In dichloromethane;
DOI:10.1016/0008-6215(91)89008-4