1'-[2-(diphenylphosphino)ethyl]-2,5-dicyclohexyl-1-phosphaferrocene

Base Information

Chemical Name:1'-[2-(diphenylphosphino)ethyl]-2,5-dicyclohexyl-1-phosphaferrocene
CAS No.:803740-07-0
Molecular Formula:C₃₅H₄₂FeP₂
Molecular Weight:580.513
Hs Code.:

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Chemical Property of 1'-[2-(diphenylphosphino)ethyl]-2,5-dicyclohexyl-1-phosphaferrocene

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Technology Process of 1'-[2-(diphenylphosphino)ethyl]-2,5-dicyclohexyl-1-phosphaferrocene

There total 1 articles about 1'-[2-(diphenylphosphino)ethyl]-2,5-dicyclohexyl-1-phosphaferrocene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 55.0%

: 448901-38-0
1-phenyl-2,5-dicyclohexylphosphole

: 803739-88-0
(η6-mesitylene) [η5-(2-(diphenylphosphino)ethyl)cyclopentadienyl]iron(II) hexafluorophosphate

: 803740-07-0
1'-[2-(diphenylphosphino)ethyl]-2,5-dicyclohexyl-1-phosphaferrocene

Guidance literature:: With Li; In 1,4-dioxane; (N2 or Ar); using Schlenk techniques; addn. of Li to soln. of 2,5-dicyclohexyl-1-phenylphosphole in dioxane at room temp.; stirring at 40°C; addn. to soln. of (PPh2C2H4C5H4)Fe(C6H3Me3) in 1,4-dioxane at 100°C; stirring for 2 h at this temp; cooling, addn. of benzene; filtration through Celite, evapn. to dryness under reduced pressure, chromy. on silica gel (elution with hexane/toluene =4/1) under N2; elem. anal.;
DOI:10.1016/j.ica.2004.05.019

Reference yield: 99.0%

: 12107-56-1
dichloro(1,5-cyclooctadiene)palladium(II)

: 803740-07-0
1'-[2-(diphenylphosphino)ethyl]-2,5-dicyclohexyl-1-phosphaferrocene

: 803739-95-9
dichloro[1'-[2-(diphenylphosphino)ethyl]-2,5-dicyclohexyl-1-phosphaferrocene]palladium(II)

Guidance literature:: In dichloromethane; byproducts: cod; (N2 or Ar); using Schlenk techniques; stirring of equimolar mixt. of PdCl2(cod) and (PPh2CH2CH2C5H4)Fe(C4H2PCy2) in CH2Cl2 for 30 min at room temp.; removal of all volatiles under reduced pressure, dissolving in min. amt.of CH2Cl2; recrystn. by slow diffusion of pentane into the CH2Cl2 soln. at room temp.; elem. anal.;
DOI:10.1016/j.ica.2004.05.019

Reference yield:

: 12107-56-1
dichloro(1,5-cyclooctadiene)palladium(II)

: 803740-07-0
1'-[2-(diphenylphosphino)ethyl]-2,5-dicyclohexyl-1-phosphaferrocene

: [Cl₂Pd((P(C₆H₅)2CH₂CH₂C₅H₄)Fe(C₄H₂P(C₆H₁₁)2))2]

Guidance literature:: In chloroform-d1; byproducts: cod; (N2 or Ar); using Schlenk techniques; treatment of (PPh2CH2CH2C5H4)Fe(C4H2PCy)2 (PP2) with PdCl2(cod) (6) in CDCl2 at molar ratio (PP2/6=2) at room temp.; monitoring by NMR;
DOI:10.1016/j.ica.2004.05.019