Phosphorodichloridic acid, 3-methylbutyl ester

Base Information

• Chemical Name: Phosphorodichloridic acid, 3-methylbutyl ester
• CAS No.: 114503-61-6
• Molecular Formula: C5H11Cl2O2P
• Molecular Weight: 205.021
• Mol file: 114503-61-6.mol

Synonyms:

Chemical Property of Phosphorodichloridic acid, 3-methylbutyl ester

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of Phosphorodichloridic acid, 3-methylbutyl ester

There total 2 articles about Phosphorodichloridic acid, 3-methylbutyl ester which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

C11H20NO2S2(1+)*Cl2O2P(1-) → C6H11ClOS + dichlorophosphoric acid isopentyl ester (114503-61-6) + 1-chloro-3-methylbutane (107-84-6)

Guidance literature:

In diethyl ether; acetonitrile; at -5 - 20 ℃;

DOI:10.1055/s-2006-950356

Reference yield:

Phenyl-phosphonothioic acid O,O-bis-(3-methyl-butyl) ester → dichlorophosphoric acid isopentyl ester (114503-61-6) + C11H16ClOPS

Guidance literature:

With trichlorophosphate; at 90 ℃; for 10.5h;

Reference yield:

dichlorophosphoric acid isopentyl ester (114503-61-6) + sodium 3-methylphenoxide (3019-89-4) → phosphoric acid isopentyl ester-di-m-tolyl ester

Guidance literature:

With xylene;

Refernces

• 1、 Tang, Chu Chi,Wu, Gui Ping,Huang, Guang Yan,Li, Zhen,Jin, Gui Yu. "THE ISOMERIZATION/CHLORINATION OF O,O-DIALKYL PHENYLTHIOPHOSPHONATES WITH PHOSPHORUS OXYCHLORIDE - A NEW CONVENIENT SYNTHESIS OF S-ALKYL PHENYLTHIOPHOSPHONIC ACID DERIVATIVES". . p. 159 - 164. Retrieved 2007/10/02.