1-(2-[[(2,6-dimethylphenyl)imino](phenyl)methyl]-1',2',3',4',5'-pentamethylrhodocen-1-yl)-2,2,2-trifluoroethanone chloride

Base Information

• Chemical Name: 1-(2-[[(2,6-dimethylphenyl)imino](phenyl)methyl]-1',2',3',4',5'-pentamethylrhodocen-1-yl)-2,2,2-trifluoroethanone chloride
• CAS No.: 1315085-50-7
• Molecular Formula: C₃₂H₃₂F₃NORh*Cl
• Molecular Weight: 641.966
• Mol file: 1315085-50-7.mol

Synonyms:

Chemical Property of 1-(2-[[(2,6-dimethylphenyl)imino](phenyl)methyl]-1',2',3',4',5'-pentamethylrhodocen-1-yl)-2,2,2-trifluoroethanone chloride

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of 1-(2-[[(2,6-dimethylphenyl)imino](phenyl)methyl]-1',2',3',4',5'-pentamethylrhodocen-1-yl)-2,2,2-trifluoroethanone chloride

There total 1 articles about 1-(2-[[(2,6-dimethylphenyl)imino](phenyl)methyl]-1',2',3',4',5'-pentamethylrhodocen-1-yl)-2,2,2-trifluoroethanone chloride which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 44.0%

dichloro(pentamethylcyclopentadienyl)rhodium (III) dimer + 1-[5-[1-[N-(2,6-dimethylphenyl)amino]-1-phenylmethylene]cyclopenta-1,3-dien-1-yl]-2,2,2-trifluoroethanone (1189541-23-8) → 1-(2-[[(2,6-dimethylphenyl)imino](phenyl)methyl]-1',2',3',4',5'-pentamethylrhodocen-1-yl)-2,2,2-trifluoroethanone chloride (1315085-50-7)

Guidance literature:

With KH; In tetrahydrofuran; byproducts: H2; (Ar), pentafulvene in dry THF cooled to 0°C, treated with excess KH, stirred, warmed to room temp., stirred overnight, filtered, treated with Rh complex (0.5 equiv.), stirred at room temp. for 4 d; evapd.(vac.), exposed to air, hydrolized (H2O), extd.(CH2Cl2), org. layer dried (brine with Na2SO4), evapd.(vac.), chromy.(silica - CH2Cl2, CH3OH), evapd., elem. anal.;

DOI:10.1002/ejic.201100226

upstream raw materials:

1-[5-[1-[N-(2,6-dimethylphenyl)amino]-1-phenylmethylene]cyclopenta-1,3-dien-1-yl]-2,2,2-trifluoroethanone