(η5-pentamethylcyclopentadienyl)(η5-B-phenylborole)rhodium

Base Information

• Chemical Name: (η5-pentamethylcyclopentadienyl)(η5-B-phenylborole)rhodium
• CAS No.: 1001100-73-7
• Molecular Formula: C₂₀H₂₄BRh
• Molecular Weight: 378.127
• Mol file: 1001100-73-7.mol

Synonyms:

Chemical Property of (η5-pentamethylcyclopentadienyl)(η5-B-phenylborole)rhodium

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of (η5-pentamethylcyclopentadienyl)(η5-B-phenylborole)rhodium

There total 1 articles about (η5-pentamethylcyclopentadienyl)(η5-B-phenylborole)rhodium which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 44.0%

Rh4(μ3-I)4(C4H4BPh)4 + lithiumpentamethylcyclopentadiene → (η5-pentamethylcyclopentadienyl)(η5-B-phenylborole)rhodium (1001100-73-7)

Guidance literature:

In tetrahydrofuran; mixt. of Rh complex and (C5Me5)Li in THF stirred for 24 h; evapd. under vac., chromy. (silica, petroleum ether), yellow fraction evapd. under vac.; elem. anal.;

DOI:10.1007/s11172-006-0457-y

Reference yield: 95.0%

bis[dichloro(pentamethylcyclopentadienyl)iridium(III)] (12354-84-6,12354-85-7) + silver tetrafluoroborate tris(tetrahydrofuranate) + (η5-pentamethylcyclopentadienyl)(η5-B-phenylborole)rhodium (1001100-73-7) → [(η5-pentamethylcyclopentadienyl)iridium](μ-η5:η5-B-phenylborole)[(η5-pentamethylcyclopentadienyl)rhodium] bis(tetrafluoroborate)

Guidance literature:

In nitromethane; byproducts: AgCl; nitromethane added to mixt. of (C5Me5IrCl2)2 and AgBF4*3dioxane, stirredfor 0.5 h, ppt. removed by centrifugation, soln. added to borole comple x, mixt. stirred for 2 h; Et2O added, ppt. filtered off, repptd. twice acetone/Et2O or CH2Cl2/Et2O; elem. anal.;

DOI:10.1007/s11172-006-0457-y

Reference yield: 86.0%

dichloro(pentamethylcyclopentadienyl)rhodium (III) dimer + silver tetrafluoroborate tris(tetrahydrofuranate) + (η5-pentamethylcyclopentadienyl)(η5-B-phenylborole)rhodium (1001100-73-7) → [(η5-pentamethylcyclopentadienyl)rhodium](μ-η5:η5-B-phenylborole)[(η5-pentamethylcyclopentadienyl)rhodium] bis(tetrafluoroborate)

Guidance literature:

In nitromethane; byproducts: AgCl; nitromethane added to mixt. pf (C5Me5RhCl2)2 and AgBF4*3dioxane, stirredfor 0.5 h, ppt. removed by centrifugation, soln. added to borole comple x, mixt. stirred for 2 h; Et2O added, ppt. filtered off, repptd. twice from acetone/Et2O or CH2Cl2/Et2O; elem. anal.;

DOI:10.1007/s11172-006-0457-y