Mo(η6-PhPPh2)(dppm)(PPh3)

Base Information

Chemical Name:Mo(η6-PhPPh2)(dppm)(PPh3)
CAS No.:122068-47-7
Molecular Formula:C₆₁H₅₂MoP₄
Molecular Weight:1004.92
Hs Code.:

Synonyms:

Suppliers and Price of Mo(η6-PhPPh2)(dppm)(PPh3)

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 0 raw suppliers

Chemical Property of Mo(η6-PhPPh2)(dppm)(PPh3)

Chemical Property:

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Technology Process of Mo(η6-PhPPh2)(dppm)(PPh3)

There total 1 articles about Mo(η6-PhPPh2)(dppm)(PPh3) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 10.0%

: 122068-49-9
MoCl₄(dppm)

: 603-35-0
triphenylphosphine

: 122068-47-7
Mo(η6-PhPPh2)(dppm)(PPh3)

Guidance literature:: With Na/Hg amalgam; In tetrahydrofuran; dissolving of PPh3 in double-distd. THF under Ar, addn. of MoCl4(dppm), vigorous stirring (5 min), addn. of Na/Hg amalgam, thorough degassing, color change from brown, red, dirty green to brown (during the first 15 min), vigorous stirring (2 h); sepn. from Na/Hg by a cannula, filtration (Celite), reducing of vol., dropwise addn. of methanol to a dark reddish brown air-sensitive product, dissolving in benzene, chromy. (Al2O3 under N2), crystn. (benzene/methanol); elem. anal.;

Reference yield: 66.0%

: tetrafluoroboric acid

: 122068-47-7
Mo(η6-PhPPh2)(dppm)(PPh3)

: Mo(η6-C6H6)(dppm)(PPh2OH)(H)(1+)*BF4(1-)

Guidance literature:: In water; benzene; byproducts: HPPh3(1+), HPPh2CH2CH2PPh2(1+), PPh3; dropwise addn. of aq. HBF4 to a soln. of the complex in water-satd. benzene (room temp.), formation of a brown oil (after 5 min) and a colorless benzene supernatant (after 10 min), removing of benzene and water; dry-pumping of the residue, redissolving in acetone;