(S)-4-Methylene-3-[2-[(1R,3aS,7aR)-7a-methyl-1-((E)-(1R,4R)-6,6,6-trifluoro-5-hydroxy-1,4-dimethyl-5-trifluoromethyl-hex-2-enyl)-octahydro-inden-(4E)-ylidene]-eth-(Z)-ylidene]-cyclohexanol

Base Information

Chemical Name:(S)-4-Methylene-3-[2-[(1R,3aS,7aR)-7a-methyl-1-((E)-(1R,4R)-6,6,6-trifluoro-5-hydroxy-1,4-dimethyl-5-trifluoromethyl-hex-2-enyl)-octahydro-inden-(4E)-ylidene]-eth-(Z)-ylidene]-cyclohexanol
CAS No.:116498-37-4
Molecular Formula:C₂₈H₃₈F₆O₂
Molecular Weight:520.599
Hs Code.:

(S)-4-Methylene-3-[2-[(1R,3aS,7aR)-7a-methyl-1-((E)-(1R,4R)-6,6,6-trifluoro-5-hydroxy-1,4-dimethyl-5-trifluoromethyl-hex-2-enyl)-octahydro-inden-(4E)-ylidene]-eth-(Z)-ylidene]-cyclohexanol

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Chemical Property of (S)-4-Methylene-3-[2-[(1R,3aS,7aR)-7a-methyl-1-((E)-(1R,4R)-6,6,6-trifluoro-5-hydroxy-1,4-dimethyl-5-trifluoromethyl-hex-2-enyl)-octahydro-inden-(4E)-ylidene]-eth-(Z)-ylidene]-cyclohexanol

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Technology Process of (S)-4-Methylene-3-[2-[(1R,3aS,7aR)-7a-methyl-1-((E)-(1R,4R)-6,6,6-trifluoro-5-hydroxy-1,4-dimethyl-5-trifluoromethyl-hex-2-enyl)-octahydro-inden-(4E)-ylidene]-eth-(Z)-ylidene]-cyclohexanol

There total 6 articles about (S)-4-Methylene-3-[2-[(1R,3aS,7aR)-7a-methyl-1-((E)-(1R,4R)-6,6,6-trifluoro-5-hydroxy-1,4-dimethyl-5-trifluoromethyl-hex-2-enyl)-octahydro-inden-(4E)-ylidene]-eth-(Z)-ylidene]-cyclohexanol which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 116355-97-6
3-methyl-4-phenylsulfonyl-1,1,1-trifluoro-2-trifluoromethylbutane-2-ol 2-methoxymethyl ether

: 116498-37-4
(S)-4-Methylene-3-[2-[(1R,3aS,7aR)-7a-methyl-1-((E)-(1R,4R)-6,6,6-trifluoro-5-hydroxy-1,4-dimethyl-5-trifluoromethyl-hex-2-enyl)-octahydro-inden-(4E)-ylidene]-eth-(Z)-ylidene]-cyclohexanol

Guidance literature:: Multi-step reaction with 4 steps

1: MgBr₂*Et₂O, LDA / tetrahydrofuran; diethyl ether / 1 h / -78 °C

2: 96 percent / p-TsOH / methanol / Ambient temperature

3: p-TsOH / methanol; CH₂Cl₂ / Heating

4: 1.)photoirradiation, EtOH-benzene, 5 min. 2.) reflux, 1h

With toluene-4-sulfonic acid; magnesium bromide; lithium diisopropyl amide; In tetrahydrofuran; methanol; diethyl ether; dichloromethane;
DOI:10.1016/S0040-4039(00)80061-1

Reference yield:

: 93748-51-7
(S)-2-[(3S,9S,10R,13R,14R,17R)-10,13-Dimethyl-3-(tetrahydro-pyran-2-yloxy)-2,3,4,9,10,11,12,13,14,15,16,17-dodecahydro-1H-cyclopenta[a]phenanthren-17-yl]-propionaldehyde

: 116498-37-4
(S)-4-Methylene-3-[2-[(1R,3aS,7aR)-7a-methyl-1-((E)-(1R,4R)-6,6,6-trifluoro-5-hydroxy-1,4-dimethyl-5-trifluoromethyl-hex-2-enyl)-octahydro-inden-(4E)-ylidene]-eth-(Z)-ylidene]-cyclohexanol

Guidance literature:: Multi-step reaction with 4 steps

1: MgBr₂*Et₂O, LDA / tetrahydrofuran; diethyl ether / 1 h / -78 °C

2: 96 percent / p-TsOH / methanol / Ambient temperature

3: p-TsOH / methanol; CH₂Cl₂ / Heating

4: 1.)photoirradiation, EtOH-benzene, 5 min. 2.) reflux, 1h

With toluene-4-sulfonic acid; magnesium bromide; lithium diisopropyl amide; In tetrahydrofuran; methanol; diethyl ether; dichloromethane;
DOI:10.1016/S0040-4039(00)80061-1

Reference yield:

: 116355-98-7,116498-39-6,117467-31-9
C₄₁H₅₆F₆O₇S

: 116498-37-4
(S)-4-Methylene-3-[2-[(1R,3aS,7aR)-7a-methyl-1-((E)-(1R,4R)-6,6,6-trifluoro-5-hydroxy-1,4-dimethyl-5-trifluoromethyl-hex-2-enyl)-octahydro-inden-(4E)-ylidene]-eth-(Z)-ylidene]-cyclohexanol

Guidance literature:: Multi-step reaction with 3 steps

1: 96 percent / p-TsOH / methanol / Ambient temperature

2: p-TsOH / methanol; CH₂Cl₂ / Heating

3: 1.)photoirradiation, EtOH-benzene, 5 min. 2.) reflux, 1h

With toluene-4-sulfonic acid; In methanol; dichloromethane;
DOI:10.1016/S0040-4039(00)80061-1