dichloro-(η**(4)-dicyclopentadiene)platinum(II)

Base Information

• Chemical Name: dichloro-(η**(4)-dicyclopentadiene)platinum(II)
• CAS No.: 33594-01-3
• Molecular Formula: C₁₀H₁₂Cl₂Pt
• Molecular Weight: 398.191
• Mol file: 33594-01-3.mol

Synonyms:

Chemical Property of dichloro-(η**(4)-dicyclopentadiene)platinum(II)

Chemical Property:

Purity/Quality:

Safty Information:

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Useful:

Technology Process of dichloro-(η**(4)-dicyclopentadiene)platinum(II)

There total 1 articles about dichloro-(η**(4)-dicyclopentadiene)platinum(II) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 61.0%

dihydrogen hexachloroplatinate + bi(cyclopentadiene) (77-73-6,933-60-8,1755-01-7,25038-78-2) → dichloro-(η**(4)-dicyclopentadiene)platinum(II) (12083-92-0,33594-01-3)

Guidance literature:

With NaOH; TBACl; N₂H₄*2HCl; In water; 1,2-dichloro-ethane; under N2; to mixt. of aq. H2PtCl6, ClCH2CH2Cl, water, TBACl and diene added soln. of NaOH in portions until basic pH of aq. layer; then N2H4*2HCl in H2O added under stirring at room temp/; refluxed for 6 h; aq. layer discarded; ppt. washed with heptane, dried in vac.; elem. anal.;

DOI:10.1016/j.jorganchem.2010.12.043

Reference yield: 91.0%

dichloro-(η**(4)-dicyclopentadiene)platinum(II) (12083-92-0,33594-01-3) + methyl (R)-2-(N,N-methyl-[(R)-(dinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepin-2-yl)]amino)-3-phenylpropionate → cis-dichloridobis[methyl (R)-2-(N,N-methyl-[(R)-(dinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepin-2-yl)]amino)-3-phenylpropionate]platinum(II)

Guidance literature:

In dichloromethane; N2, stoich., stirred at room temp. for 24 h; concd., pentane added, cooled to -10°C; elem. anal.;

DOI:10.1002/ejic.200700474

Reference yield: 80.0%

dichloro-(η**(4)-dicyclopentadiene)platinum(II) (12083-92-0,33594-01-3) + methyl (triphenylphosphoranylidene)acetate (21204-67-1,2605-67-6) → [PtCl2(η3-C10H12CH(PPh3)CO2Me]

Guidance literature:

In acetone; addn. of equimolar amt. of Ph3PCHCO2Me to rapidly stirred soln. of PtCl2(C10H12) in Me2CO; stirring for 24 h; pptn., concn., addn. of Et2O, pptn., washing with Et2O, drying, as mixt.of two diastereoisomers, elem. anal.;

DOI:10.1021/om020970q

upstream raw materials:

bi(cyclopentadiene)