Technology Process of Manganese, dibromo(dimethylphenylphosphine)-
There total 2 articles about Manganese, dibromo(dimethylphenylphosphine)- which
guide to synthetic route it.
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synthetic route:
- Guidance literature:
-
With
P(C6H5)(CH3)2;
In
dichloromethane; toluene;
ligand was added to the soln. of MnBr2 in mixt. of solvents, the mixt. was stirred under Ar for 5 d at 25°C; the soln. was reduced in vac. at 25°C, filteres, ppt. was washedwith CH2Cl2, dried in vac.;
DOI:10.1016/S0020-1693(00)87987-6
- Guidance literature:
-
MnBr2 was sublimed into a KBr infrared window followed by heating at 473 K in a specially designed infrared cell at 1E-6 torr; the dry film wasexposed to PPhMe2;; extensive evacuation at 1E-6 torr; complex obtained as film;;
- Guidance literature:
-
With
CS2;
In
diethyl ether;
the soln. of Mn complex was refluxed under Ar, excess CS2 was added, the mixt. was refluxed for 48 h; the mixt. was cooled to 25°C, filtered, ppt. was washed with ether, dried in vac. for 6 h at 25°C, elem. anal.;
DOI:10.1016/S0020-1693(00)87987-6
