C₆H₅Cr(CO)3C(O)Mn(CO)3(P(C₆H₅)2C₂H₄P(C₆H₅)2)

Base Information

• Chemical Name: C₆H₅Cr(CO)3C(O)Mn(CO)3(P(C₆H₅)2C₂H₄P(C₆H₅)2)
• CAS No.: 138090-91-2
• Molecular Formula: C₃₉H₂₉CrMnO₇P₂
• Molecular Weight: 778.537
• Mol file: 138090-91-2.mol

Synonyms:

Chemical Property of C₆H₅Cr(CO)3C(O)Mn(CO)3(P(C₆H₅)2C₂H₄P(C₆H₅)2)

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of C₆H₅Cr(CO)3C(O)Mn(CO)3(P(C₆H₅)2C₂H₄P(C₆H₅)2)

There total 1 articles about C₆H₅Cr(CO)3C(O)Mn(CO)3(P(C₆H₅)2C₂H₄P(C₆H₅)2) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 52.0%

bromopentacarbonylmanganese(I) (14516-54-2) + (benzene)tricarbonylchromium (697302-50-4,697302-51-5,12082-08-5,697302-53-7) + 1,2-bis-(diphenylphosphino)ethane (1663-45-2) → ((C6H5)2CO)(Cr(CO)3)2 (57347-34-9) + C6H5Cr(CO)3C(O)Mn(CO)3(P(C6H5)2C2H4P(C6H5)2) (138090-91-2)

Guidance literature:

With n-BuLi; In tetrahydrofuran; under N2; addn. of n-BuLi to a well-stirred soln. of Cr-compd. (-78.degrree.C), warmed slowly to -30°C, stirred for 20 min, cooled to -78°C, added to stirred soln. of Mn-compd. (-30°C), addn. of ligand, stirred at room temp.; evapd., column chromy. (silica gel, CH2Cl2/hexane 1:1), orange band collected, evapd.; elem. anal.;

upstream raw materials:

bromopentacarbonylmanganese(I)

(benzene)tricarbonylchromium

1,2-bis-(diphenylphosphino)ethane