C₆₀H₁₀₂Cl₂O₂P₄Ru₂

Base Information

• Chemical Name: C₆₀H₁₀₂Cl₂O₂P₄Ru₂
• CAS No.: 1401255-06-8
• Molecular Formula: C₆₀H₁₀₂Cl₂O₂P₄Ru₂
• Molecular Weight: 1252.41
• Mol file: 1401255-06-8.mol

Synonyms:

Chemical Property of C₆₀H₁₀₂Cl₂O₂P₄Ru₂

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of C₆₀H₁₀₂Cl₂O₂P₄Ru₂

There total 4 articles about C₆₀H₁₀₂Cl₂O₂P₄Ru₂ which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 82.7%

1,2-bis(4-ethynylphenyl)cyclohex-1-ene (1401255-12-6) + C19H43ClOP2Ru (102513-17-7) → C60H102Cl2O2P4Ru2 (1401255-06-8)

Guidance literature:

In dichloromethane; at 23 ℃; for 0.5h; Inert atmosphere; Schlenk technique;

DOI:10.1021/ja3059606

Reference yield:

1,2-bis((4-(trimethylsilyl)ethynyl)phenyl)cyclohex-1-ene (1401255-11-5) → C60H102Cl2O2P4Ru2 (1401255-06-8)

Guidance literature:

Multi-step reaction with 2 steps

1.1: ammonium fluoride / tetrahydrofuran; methanol / 18 h / 23 °C / Inert atmosphere

1.2: 1 h / Inert atmosphere

2.1: dichloromethane / 0.5 h / 23 °C / Inert atmosphere; Schlenk technique

With ammonium fluoride; In tetrahydrofuran; methanol; dichloromethane;

DOI:10.1021/ja3059606

Reference yield:

(Z)-4,4'-dibromostilbene (23958-29-4) → C60H102Cl2O2P4Ru2 (1401255-06-8)

Guidance literature:

Multi-step reaction with 4 steps

1.1: n-butyllithium / tetrahydrofuran / 0.25 h / -78 °C / Inert atmosphere

1.2: 0.75 h / -78 - 23 °C / Inert atmosphere

2.1: bis-triphenylphosphine-palladium(II) chloride; copper(l) iodide; triethylamine / tetrahydrofuran / 23 °C / Inert atmosphere

3.1: ammonium fluoride / tetrahydrofuran; methanol / 18 h / 23 °C / Inert atmosphere

3.2: 1 h / Inert atmosphere

4.1: dichloromethane / 0.5 h / 23 °C / Inert atmosphere; Schlenk technique

With bis-triphenylphosphine-palladium(II) chloride; ammonium fluoride; copper(l) iodide; n-butyllithium; triethylamine; In tetrahydrofuran; methanol; dichloromethane; 2.1: |Sonogashira Cross-Coupling;

DOI:10.1021/ja3059606

upstream raw materials:

1,2-bis((4-(trimethylsilyl)ethynyl)phenyl)cyclohex-1-ene

1,2-bis(4-ethynylphenyl)cyclohex-1-ene

C₁₉H₄₃ClOP₂Ru

(Z)-4,4'-dibromostilbene