C₆H₅NiP(C₆H₅)3C₇H₅ONC₆H₃CH₃C(CH₃)3

Base Information

• Chemical Name: C₆H₅NiP(C₆H₅)3C₇H₅ONC₆H₃CH₃C(CH₃)3
• CAS No.: 336627-81-7
• Molecular Formula: C₄₂H₄₀NNiOP
• Molecular Weight: 664.449
• Mol file: 336627-81-7.mol

Synonyms:

Chemical Property of C₆H₅NiP(C₆H₅)3C₇H₅ONC₆H₃CH₃C(CH₃)3

Chemical Property:

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Useful:

Technology Process of C₆H₅NiP(C₆H₅)3C₇H₅ONC₆H₃CH₃C(CH₃)3

There total 1 articles about C₆H₅NiP(C₆H₅)3C₇H₅ONC₆H₃CH₃C(CH₃)3 which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 47.0%

bis(triphenylphosphine)nickel phenyl chloride + 2-(2-tert-butylanilino)tropone sodium salt*1.16THF → C6H5NiP(C6H5)3C7H5ONC6H3CH3C(CH3)3 (336627-81-7)

Guidance literature:

In tetrahydrofuran; byproducts: NaCl; (Ar); addn. of THF to a mixt. of ligand and nickel complex at -30°C, warming to room temp. for 1 h, stirring for 1 h; evapn., dissolving in toluene, filtration through Celite with toluene, concn., addn. of pentane, cooling to -30°C overnight, filtration, washing ppt. with pentane, drying in vac.; elem. anal.;

DOI:10.1021/om030142c