(1R,3aS,4S,7aR)-1-((R)-1,5-Dimethyl-hexyl)-7a-methyl-4-((E)-2-o-tolyl-vinyl)-octahydro-indene

Base Information

Chemical Name:(1R,3aS,4S,7aR)-1-((R)-1,5-Dimethyl-hexyl)-7a-methyl-4-((E)-2-o-tolyl-vinyl)-octahydro-indene
CAS No.:75477-04-2
Molecular Formula:C₂₇H₄₂
Molecular Weight:366.63
Hs Code.:

Synonyms:

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Chemical Property of (1R,3aS,4S,7aR)-1-((R)-1,5-Dimethyl-hexyl)-7a-methyl-4-((E)-2-o-tolyl-vinyl)-octahydro-indene

Chemical Property:

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Technology Process of (1R,3aS,4S,7aR)-1-((R)-1,5-Dimethyl-hexyl)-7a-methyl-4-((E)-2-o-tolyl-vinyl)-octahydro-indene

There total 19 articles about (1R,3aS,4S,7aR)-1-((R)-1,5-Dimethyl-hexyl)-7a-methyl-4-((E)-2-o-tolyl-vinyl)-octahydro-indene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 26358-65-6
5α-cholestane-3β,6β-diol 6-acetate

: 75477-04-2
(1R,3aS,4S,7aR)-1-((R)-1,5-Dimethyl-hexyl)-7a-methyl-4-((E)-2-o-tolyl-vinyl)-octahydro-indene

Guidance literature:: Multi-step reaction with 15 steps

1: 22 g / triphenylphosphine, diethyl azodicarboxylate / tetrahydrofuran / 15 h

2: 2.) KOH / 1.) chlorination, 2.) H₂O, EtOH

3: 11 g / pyridine / 16 h / 25 °C

4: 5.9 g / phosphoryl chloride, pyridine / 20 h / 20 °C

5: 3.2 g / KOH / methanol; benzene / 12 h / 20 °C

6: Jones reagent / acetone / 0.17 h

7: H₂SO₄ / acetone / 16 h

8: 500 mg / dichlorodicyanobenzoquinone / benzene / 24 h / Heating

9: 90 percent / m-chloroperbenzoic acid / CH₂Cl₂

10: 190 mg / LiAlH₄ / tetrahydrofuran / 16 h / Heating

11: pyridinium chlorochromate / CH₂Cl₂ / Ambient temperature

12: 140 mg / boron trifluoride etherate / acetic acid

13: 95 mg / W-2 Raney nickel / ethanol

14: N-bromosuccinimide, benzoyl peroxide / CCl₄ / 0.75 h / Heating

15: potassium t-butoxide / tetrahydrofuran; 2-methyl-propan-2-ol / 5 h / Heating

With pyridine; potassium hydroxide; N-Bromosuccinimide; lithium aluminium tetrahydride; Perbenzoic acid; jones reagent; W-2 Raney nickel; sulfuric acid; boron trifluoride diethyl etherate; potassium tert-butylate; 3-chloro-benzenecarboperoxoic acid; triphenylphosphine; pyridinium chlorochromate; 2,3-dicyano-5,6-dichloro-p-benzoquinone; diethylazodicarboxylate; trichlorophosphate; In tetrahydrofuran; methanol; tetrachloromethane; ethanol; dichloromethane; acetic acid; acetone; tert-butyl alcohol; benzene;

Reference yield:

: 75415-41-7
3α-hydroxycholesta-5,9(11)-diene

: 75477-04-2
(1R,3aS,4S,7aR)-1-((R)-1,5-Dimethyl-hexyl)-7a-methyl-4-((E)-2-o-tolyl-vinyl)-octahydro-indene

Guidance literature:: Multi-step reaction with 10 steps

1: Jones reagent / acetone / 0.17 h

2: H₂SO₄ / acetone / 16 h

3: 500 mg / dichlorodicyanobenzoquinone / benzene / 24 h / Heating

4: 90 percent / m-chloroperbenzoic acid / CH₂Cl₂

5: 190 mg / LiAlH₄ / tetrahydrofuran / 16 h / Heating

6: pyridinium chlorochromate / CH₂Cl₂ / Ambient temperature

7: 140 mg / boron trifluoride etherate / acetic acid

8: 95 mg / W-2 Raney nickel / ethanol

9: N-bromosuccinimide, benzoyl peroxide / CCl₄ / 0.75 h / Heating

10: potassium t-butoxide / tetrahydrofuran; 2-methyl-propan-2-ol / 5 h / Heating

With N-Bromosuccinimide; lithium aluminium tetrahydride; Perbenzoic acid; jones reagent; W-2 Raney nickel; sulfuric acid; boron trifluoride diethyl etherate; potassium tert-butylate; 3-chloro-benzenecarboperoxoic acid; pyridinium chlorochromate; 2,3-dicyano-5,6-dichloro-p-benzoquinone; In tetrahydrofuran; tetrachloromethane; ethanol; dichloromethane; acetic acid; acetone; tert-butyl alcohol; benzene;

Reference yield:

: 75415-38-2
5α-cholest-9(11)-en-3-one

: 75477-04-2
(1R,3aS,4S,7aR)-1-((R)-1,5-Dimethyl-hexyl)-7a-methyl-4-((E)-2-o-tolyl-vinyl)-octahydro-indene

Guidance literature:: Multi-step reaction with 9 steps

1: 150 mg / pyridinium hydrobromide perbromide / tetrahydrofuran / 1.) 0 deg C, 15 min, 2.) 20 deg C, 30 min

2: 127 mg / LiBr, Li₂CO₃ / dimethylformamide / 2 h / 135 °C

3: 90 percent / m-chloroperbenzoic acid / CH₂Cl₂

4: 190 mg / LiAlH₄ / tetrahydrofuran / 16 h / Heating

5: pyridinium chlorochromate / CH₂Cl₂ / Ambient temperature

6: 140 mg / boron trifluoride etherate / acetic acid

7: 95 mg / W-2 Raney nickel / ethanol

8: N-bromosuccinimide, benzoyl peroxide / CCl₄ / 0.75 h / Heating

9: potassium t-butoxide / tetrahydrofuran; 2-methyl-propan-2-ol / 5 h / Heating

With N-Bromosuccinimide; lithium aluminium tetrahydride; Perbenzoic acid; W-2 Raney nickel; boron trifluoride diethyl etherate; potassium tert-butylate; pyridinium hydrobromide perbromide; lithium carbonate; 3-chloro-benzenecarboperoxoic acid; pyridinium chlorochromate; lithium bromide; In tetrahydrofuran; tetrachloromethane; ethanol; dichloromethane; acetic acid; N,N-dimethyl-formamide; tert-butyl alcohol;