[(benzoyloxy)methyl]isocyanide

Base Information

• Chemical Name: [(benzoyloxy)methyl]isocyanide
• CAS No.: 52571-22-9
• Molecular Formula: C₉H₇NO₂
• Molecular Weight: 161.16
• Mol file: 52571-22-9.mol

Synonyms:

Chemical Property of [(benzoyloxy)methyl]isocyanide

Chemical Property:

Purity/Quality:

95% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of [(benzoyloxy)methyl]isocyanide

There total 1 articles about [(benzoyloxy)methyl]isocyanide which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

iodomethylbenzoate (13943-33-4) + silver(I) cyanide (506-64-9) → [(benzoyloxy)methyl]isocyanide (52571-22-9)

Guidance literature:

In chloroform;

Reference yield: 68.0%

tungsten hexacarbonyl (14040-11-0) + [(benzoyloxy)methyl]isocyanide (52571-22-9) → [((benzoyloxy)methyl)isocyanide]pentacarbonyltungsten (97385-64-3)

Guidance literature:

In tetrahydrofuran; byproducts: CO; Irradiation (UV/VIS); irradn. of W(CO)6 in THF under N2, addn. of the isocyanide, stirring (room temp., 90 min), colour change from orange to deep red, evapg. solvent (water jet vac.); drying (high vac.), sulbimation of W(CO)6 (room temp., 2 d, high vac.),dissolving in petroleum ether (60-80°C), filtration (filter cellulose), concg. (water jet vac.), crystn. (-30°C, 2 d), drying in high vac.; elem. anal.;

Reference yield: 53.0%

[(benzoyloxy)methyl]isocyanide (52571-22-9) + chromium(0) hexacarbonyl (199620-14-9,13007-92-6) → [((benzoyloxy)methyl)isocyanide]pentacarbonylchromium (97385-63-2)

Guidance literature:

In tetrahydrofuran; byproducts: CO; Irradiation (UV/VIS); irradn. of Cr(CO)6 in THF under N2, addn. of the isocyanide after completion of the CO evolving, stirring (room temp., 90 min);; evapn., drying (high vac.), sublimation of Cr(CO)6 (room temp., 2 d, high vac.), dissolving in petroleum ether (60-80°C), filtration (filter cellulose), concg. (water jet vac.), crystn. (-30°C, 2 d), drying in high vac.; elem. anal.;

upstream raw materials:

iodomethylbenzoate

silver(I) cyanide

Downstream raw materials:

bis[((benzoyloxy)methyl)isocyanide]dichloropalladium

[((benzoyloxy)methyl)isocyanide]pentacarbonyltungsten

[((benzoyloxy)methyl)isocyanide]chlorocopper

[((benzoyloxy)methyl)isocyanide]pentacarbonylchromium