Os₂Ru(P(C₆H₅)3)(CO)11

Base Information

• Chemical Name: Os₂Ru(P(C₆H₅)3)(CO)11
• CAS No.: 869477-40-7
• Molecular Formula: C₂₉H₁₅O₁₁Os₂PRu
• Molecular Weight: 1051.88
• Mol file: 869477-40-7.mol

Synonyms:

Chemical Property of Os₂Ru(P(C₆H₅)3)(CO)11

Chemical Property:

Purity/Quality:

Safty Information:

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Technology Process of Os₂Ru(P(C₆H₅)3)(CO)11

There total 1 articles about Os₂Ru(P(C₆H₅)3)(CO)11 which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 40.0%

[RuOs2(CO)12] (12389-50-3) + triphenylphosphine (603-35-0) + acetonitrile (75-05-8,26809-02-9) → Os2Ru(P(C6H5)3)(CO)11 (869477-40-7) + Os3(CO)11(PPh3) (116261-58-6,30173-88-7)

Guidance literature:

With trimethylamine N-oxide; In tetrahydrofuran; acetonitrile; N2, to a soln. of Ru compd. (THF) added a soln. of N-oxide compd. (CH3CN) at 200 K, stirred for 30 min, P compd. added, warmed to room temp., stirred for 2 d in the dark; solvent removed (vac.), chromy. (silica gel, hexane/THF), TLC, recrystd.(petroleum ether);

DOI:10.1002/ejic.200401040

upstream raw materials:

[RuOs₂(CO)12]

triphenylphosphine

acetonitrile