trans-(4-ethynylphenyl)-[5,15-bis(4-ethynylphenyl)-3,7,13,17-tetramethyl-2,8,12,18-tetrakis(n-hexyl)zinc(II)porphyrin]bis(tri-n-butyl-phosphine)platinum(II)

Base Information

Chemical Name:trans-(4-ethynylphenyl)-[5,15-bis(4-ethynylphenyl)-3,7,13,17-tetramethyl-2,8,12,18-tetrakis(n-hexyl)zinc(II)porphyrin]bis(tri-n-butyl-phosphine)platinum(II)
CAS No.:1312897-31-6
Molecular Formula:C₉₆H₁₃₄N₄P₂PtZn
Molecular Weight:1666.56
Hs Code.:

trans-(4-ethynylphenyl)-[5,15-bis(4-ethynylphenyl)-3,7,13,17-tetramethyl-2,8,12,18-tetrakis(n-hexyl)zinc(II)porphyrin]bis(tri-n-butyl-phosphine)platinum(II)

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Chemical Property of trans-(4-ethynylphenyl)-[5,15-bis(4-ethynylphenyl)-3,7,13,17-tetramethyl-2,8,12,18-tetrakis(n-hexyl)zinc(II)porphyrin]bis(tri-n-butyl-phosphine)platinum(II)

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Technology Process of trans-(4-ethynylphenyl)-[5,15-bis(4-ethynylphenyl)-3,7,13,17-tetramethyl-2,8,12,18-tetrakis(n-hexyl)zinc(II)porphyrin]bis(tri-n-butyl-phosphine)platinum(II)

There total 1 articles about trans-(4-ethynylphenyl)-[5,15-bis(4-ethynylphenyl)-3,7,13,17-tetramethyl-2,8,12,18-tetrakis(n-hexyl)zinc(II)porphyrin]bis(tri-n-butyl-phosphine)platinum(II) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 77.0%

: 1312897-17-8
trans-(4-ethynylphenyl)-[5-(4-ethynylphenyl)-15-[4-(trimethylsilyl)ethynylphenyl]-3,7,13,17-tetramethyl-2,8,12,18-tetrakis(n-hexyl)-zinc(II)-porphyrin]bis(tri-n-butyl-phosphine)-platinum(II)

: 1312897-31-6
trans-(4-ethynylphenyl)-[5,15-bis(4-ethynylphenyl)-3,7,13,17-tetramethyl-2,8,12,18-tetrakis(n-hexyl)zinc(II)porphyrin]bis(tri-n-butyl-phosphine)platinum(II)

Guidance literature:: With (C₄H₉)4NF; In tetrahydrofuran; 1 M soln. of NBu4F in THF was added to soln. of porphyrin in THF, stirred at room temp. for 1 h; evapd. in vac., crystd. from CH2Cl2-CH3OH, washed with CH3OH, coolected with CH2Cl2, evapd. in vac., crystd. from CH2Cl2-MeOH;
DOI:10.1039/c0nj00819b

Reference yield: 84.0%

: 130269-70-4
trans-(chloro)(phenylacetylide)(tri-n-butylphosphine)platinum (II)

: 1312897-31-6
trans-(4-ethynylphenyl)-[5,15-bis(4-ethynylphenyl)-3,7,13,17-tetramethyl-2,8,12,18-tetrakis(n-hexyl)zinc(II)porphyrin]bis(tri-n-butyl-phosphine)platinum(II)

: trans-bis[5-(4-ethynylphenyl)-15-[trans-bis(1,4-ethynylphenyl)bis(tri-n-butylphosphine)-platinum(II)]-3,7,13,17-tetramethyl-2,8,12,18-tetrakis(n-hexyl)-zinc(II)porphyrin]bis(tri-n-butylphosphine)-platinum(II)

Guidance literature:: With CuI; In dichloromethane; diethylamine; mixt. of porphyrin, platinum complex and CuI was dissolved in CH2Cl2/Et2NH (1:1, v/v), stirred at room temp. for 15 min; evapd. in vac., crystd. from CH2Cl2-MeOH, washed with MeOH, collected with CH2Cl2, evapd. in vac., crystd. from CH2Cl2-MeOH;
DOI:10.1039/c0nj00819b