syn/anti-((η5-C5Me5)Ru(μ-phenylmethylsilylene)(μ-hydrido))2

Base Information

Chemical Name:syn/anti-((η5-C5Me5)Ru(μ-phenylmethylsilylene)(μ-hydrido))2
CAS No.:610798-44-2
Molecular Formula:C₃₄H₄₈Ru₂Si₂
Molecular Weight:715.066
Hs Code.:

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Chemical Property of syn/anti-((η5-C5Me5)Ru(μ-phenylmethylsilylene)(μ-hydrido))2

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Technology Process of syn/anti-((η5-C5Me5)Ru(μ-phenylmethylsilylene)(μ-hydrido))2

There total 4 articles about syn/anti-((η5-C5Me5)Ru(μ-phenylmethylsilylene)(μ-hydrido))2 which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: syn-((η5-C5Me5)Ru(μ-phenylmethylsilylene))2(trimethylphosphine)(hydrido)2

: 610798-44-2,611187-75-8
syn/anti-((η5-C5Me5)Ru(μ-phenylmethylsilylene)(μ-hydrido))2

Guidance literature:: In benzene-d6; byproducts: trimethylphosphine; under Ar; (Cp*Ru(μ-SiPhMe))2(PMe3)(H)2 dissolved in benzene-d6; soln.charged in NMR tube and heated at 100 °C for 10 h; not isolated; NMR spectroscopy;
DOI:10.1021/om030429+

Reference yield:

: tetra-μ-hydrido-bis[(pentamethyl-η5-cyclopentadienyl)ruthenium]

: 776-76-1
methyldiphenylsilane

: 610798-44-2,611187-75-8
anti-((η5-C5Me5)Ru(μ-phenylmethylsilylene)(μ-hydrido))2

: 611187-75-8,610798-44-2
syn-((η5-C5Me5)Ru(μ-phenylmethylsilylene)(μ-hydrido))2

Guidance literature:: In toluene; under Ar; 2.5 molar equiv of Ph2MeSiH added with vigorous stirring to Cp*Ru(μ-H)4RuCp* in toluene; soln. allowed to react for 12 h at 25 °C; solvent removed under reduced pressure; residue washed with methanol; solid dissolved in toluene; product purified by column chromy. (neutral alumina, hexane/toluene); solvent removed under reduced pressure; diastereomers not sepd.;
DOI:10.1021/om030429+

Reference yield:

: tetra-μ-hydrido-bis[(pentamethyl-η5-cyclopentadienyl)ruthenium]

: 776-76-1
methyldiphenylsilane

: 610798-44-2,611187-75-8
anti-((η5-C5Me5)Ru(μ-phenylmethylsilylene)(μ-hydrido))2

: 611187-75-8,610798-44-2
syn-((η5-C5Me5)Ru(μ-phenylmethylsilylene)(μ-hydrido))2

Guidance literature:: In toluene; under Ar; 2.5 molar equiv of Ph2MeSiH added with vigorous stirring to Cp*Ru(μ-H)4RuCp* in toluene; soln. allowed to react for 12 h at 25 °C; solvent removed under reduced pressure; residue washed with methanol; solid dissolved in toluene; product purified by column chromy. (neutral alumina, hexane/toluene); solvent removed under reduced pressure; diastereomers not sepd.;
DOI:10.1021/om030429+