Undecylbromomagnesium

Base Information

• Chemical Name: Undecylbromomagnesium
• CAS No.: 117286-10-9
• Molecular Formula: C11H23BrMg
• Molecular Weight: 259.513
• Mol file: 117286-10-9.mol

Synonyms:undecyl magnesium bromide;undecanylmagnesium bromide;undecanemagnesium bromide;undecanyl magnesium bromide;n-undecyl magnesium bromide;n-undecanylmagnesium bromide;

Chemical Property of Undecylbromomagnesium

Chemical Property:

• PSA: 0.00000
• LogP: 5.33040

Purity/Quality:

99% ^*data from raw suppliers

Undecylmagnesiumbromide ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of Undecylbromomagnesium

There total 2 articles about Undecylbromomagnesium which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

bromoundecane (693-67-4) → undecylmagnesium bromide (117286-10-9)

Guidance literature:

With magnesium; In diethyl ether;

Reference yield:

bromoundecane (693-67-4) → undecylmagnesium bromide (117286-10-9)

Guidance literature:

With diethyl ether;

Reference yield: 95.0%

benzyl 4-oxopyridine-1(4H)-carboxylate + undecylmagnesium bromide (117286-10-9) → (2S)-benzyl 2-undecyl-4-oxo-3,4-dihydropyridine-1(2H)-carboxylate

Guidance literature:

benzyl 4-oxopyridine-1(4H)-carboxylate; With copper(I) bromide dimethylsulfide complex; (R,R)-1,2-bis(2,5-diphenylphospholanyl)ethane; In dichloromethane; at 18 - 25 ℃; for 0.0833333h; Inert atmosphere; Schlenk technique;

With boron trifluoride diethyl etherate; In dichloromethane; at -78 ℃; for 0.333333h; Inert atmosphere; Schlenk technique;

undecylmagnesium bromide; In dichloromethane; at -78 ℃; for 12h; enantioselective reaction; Inert atmosphere; Schlenk technique;

DOI:10.1002/anie.201906237

upstream raw materials:

bromoundecane

Downstream raw materials:

2,3-dimethyltetradecane

5-methyl-hexadecane

2,4,6-trimethyl-heptadecane

tridecan-2-ol