Technology Process of 5t-tert.Butyl-1r,3c-cyclohexandiol
There total 7 articles about 5t-tert.Butyl-1r,3c-cyclohexandiol which
guide to synthetic route it.
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synthetic route:
- Guidance literature:
-
Multi-step reaction with 6 steps
1: 66 percent / p-toluenesulfonic acid / toluene / 18 h / Heating
2: 48 percent / Hg(OCOCH3)2, NaBH4
3: 1.) NaH / 1.) DMF, 4h, room temperature, 2.) 12h, room temperature
4: 82 percent / saturated tartaric acid solution / 48 h
5: 22 percent / NH4 / diethyl ether / 1 h / 0 - 25 °C
With
sodium tetrahydroborate; mercury(II) diacetate; ammonia; sodium hydride; toluene-4-sulfonic acid; tartaric acid;
In
diethyl ether; toluene;
- Guidance literature:
-
Multi-step reaction with 7 steps
1: 71 percent / Na2Cr2O7*2H2O, H2SO4 conc. / diethyl ether; H2O / 1 h
2: 66 percent / p-toluenesulfonic acid / toluene / 18 h / Heating
3: 48 percent / Hg(OCOCH3)2, NaBH4
4: 1.) NaH / 1.) DMF, 4h, room temperature, 2.) 12h, room temperature
5: 82 percent / saturated tartaric acid solution / 48 h
6: 22 percent / NH4 / diethyl ether / 1 h / 0 - 25 °C
With
sodium tetrahydroborate; sodium dichromate; sulfuric acid; mercury(II) diacetate; ammonia; sodium hydride; toluene-4-sulfonic acid; tartaric acid;
In
diethyl ether; water; toluene;
- Guidance literature:
-
Multi-step reaction with 5 steps
1: 48 percent / Hg(OCOCH3)2, NaBH4
2: 1.) NaH / 1.) DMF, 4h, room temperature, 2.) 12h, room temperature
3: 82 percent / saturated tartaric acid solution / 48 h
4: 22 percent / NH4 / diethyl ether / 1 h / 0 - 25 °C
With
sodium tetrahydroborate; mercury(II) diacetate; ammonia; sodium hydride; tartaric acid;
In
diethyl ether;
