C₂₇⁽¹³⁾CH₃₂O₆

Base Information

• Chemical Name: C₂₇⁽¹³⁾CH₃₂O₆
• CAS No.: 1234880-61-5
• Molecular Formula: C₂₈H₃₂O₆
• Molecular Weight: 465.547
• Mol file: 1234880-61-5.mol

Synonyms:

Chemical Property of C₂₇⁽¹³⁾CH₃₂O₆

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of C₂₇⁽¹³⁾CH₃₂O₆

There total 7 articles about C₂₇⁽¹³⁾CH₃₂O₆ which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

C27(13)CH30O6 → C27(13)CH32O6 (1234880-61-5)

Guidance literature:

With triethylsilane; trifluoroacetic acid; In dichloromethane; at -20 - 20 ℃; Inert atmosphere;

DOI:10.2174/157017810791112478

Reference yield:

C13(13)CH18O6 → C27(13)CH32O6 (1234880-61-5)

Guidance literature:

Multi-step reaction with 2 steps

1: tetra-(n-butyl)ammonium iodide; sodium hydride / tetrahydrofuran / Inert atmosphere; Cooling; Reflux

2: triethylsilane; trifluoroacetic acid / dichloromethane / -20 - 20 °C / Inert atmosphere

With triethylsilane; tetra-(n-butyl)ammonium iodide; sodium hydride; trifluoroacetic acid; In tetrahydrofuran; dichloromethane;

DOI:10.2174/157017810791112478

Reference yield:

13C-C1-glucopyranose (40010-55-7,40010-56-8,56746-22-6,60821-16-1,60821-17-2,60821-20-7,60821-21-8) → C27(13)CH32O6 (1234880-61-5)

Guidance literature:

Multi-step reaction with 7 steps

1.1: perchloric acid / 0 - 40 °C

2.1: water; phosphorus tribromide / 15 - 25 °C

3.1: silver carbonate / dichloromethane / 0.17 h / 20 °C / Inert atmosphere; Darkness; Molecular sieve

3.2: 0.5 h / Inert atmosphere; Darkness; Molecular sieve

4.1: sodium methylate / methanol; dichloromethane / 15 h / 20 °C / Inert atmosphere

4.2: Dowex 50W-8X (H+)

5.1: toluene-4-sulfonic acid / N,N-dimethyl-formamide / 2 h / 50 °C / 37.5 Torr

6.1: tetra-(n-butyl)ammonium iodide; sodium hydride / tetrahydrofuran / Inert atmosphere; Cooling; Reflux

7.1: triethylsilane; trifluoroacetic acid / dichloromethane / -20 - 20 °C / Inert atmosphere

With triethylsilane; perchloric acid; water; sodium methylate; phosphorus tribromide; tetra-(n-butyl)ammonium iodide; sodium hydride; toluene-4-sulfonic acid; silver carbonate; trifluoroacetic acid; In tetrahydrofuran; methanol; dichloromethane; N,N-dimethyl-formamide;

DOI:10.2174/157017810791112478

upstream raw materials:

methyl [1-13C]-2,3,4,6-tetra-O-acetyl-β-D-glucoside

penta-O-acetyl-β-D-<1-13C>glucose

¹³C-C₁-glucopyranose

2,3,4,6-Tetra-O-acetyl-1-bromo<1-¹³C>-α-D-glucopyranose

Downstream raw materials:

C₂₈⁽¹³⁾CH₃₄O₆