(4-amino-6-methyl-1,2,4-triazine-3-thione-5-one)(PPh₃)2CuCl

Base Information

• Chemical Name: (4-amino-6-methyl-1,2,4-triazine-3-thione-5-one)(PPh₃)2CuCl
• CAS No.: 512837-04-6
• Molecular Formula: C₄₀H₃₆ClCuN₄OP₂S
• Molecular Weight: 781.765
• Mol file: 512837-04-6.mol

Synonyms:

Chemical Property of (4-amino-6-methyl-1,2,4-triazine-3-thione-5-one)(PPh₃)2CuCl

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of (4-amino-6-methyl-1,2,4-triazine-3-thione-5-one)(PPh₃)2CuCl

There total 2 articles about (4-amino-6-methyl-1,2,4-triazine-3-thione-5-one)(PPh₃)2CuCl which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 95.0%

4-amino-5-oxo-3-thioxo-6-methyl-2,3,4,5-tetrahydro<1,2,4>triazine (22278-81-5) + triphenylphosphine (603-35-0) + copper(l) chloride → (4-amino-6-methyl-1,2,4-triazine-3-thione-5-one)(PPh3)2CuCl (512837-04-6)

Guidance literature:

In chloroform; acetonitrile; 1 equiv. of MeCN soln. of N-base was added to 1 equiv. of CuCl and 2 equiv. of PPh3 in CHCl3, stirring for 3 h, reflux; soln. vol. was concd., crystn. at 20 °C for several d, crystals were washed with MeOH and dried in air, elem. anal.;

DOI:10.1002/1521-3749(200213)628:13<2887::AID-ZAAC2887>3.0.CO;2-B

Reference yield:

bis(4-amino-κN-3-thioxo-κS-6-methyl-2,3,4,5-tetrahydro-1,2,3-triazin-5-one)copper(I) chloride (124261-81-0) + triphenylphosphine (603-35-0) → (4-amino-6-methyl-1,2,4-triazine-3-thione-5-one)(PPh3)2CuCl (512837-04-6)

Guidance literature:

In chloroform; acetonitrile; byproducts: 4-amino-6-methyl-1,2,4-triazine-3-thione-5-one; reflux;

DOI:10.1002/1521-3749(200213)628:13<2887::AID-ZAAC2887>3.0.CO;2-B

upstream raw materials:

4-amino-5-oxo-3-thioxo-6-methyl-2,3,4,5-tetrahydro<1,2,4>triazine

triphenylphosphine

bis(4-amino-κN-3-thioxo-κS-6-methyl-2,3,4,5-tetrahydro-1,2,3-triazin-5-one)copper(I) chloride