dihydride(1,4-biscyclohexyl-diaza-1,3-butadiene)bis(4-fluor-tristriphenylphosphine)rhodium(III) perchlorate

Base Information

• Chemical Name: dihydride(1,4-biscyclohexyl-diaza-1,3-butadiene)bis(4-fluor-tristriphenylphosphine)rhodium(III) perchlorate
• CAS No.: 115564-83-5
• Molecular Formula: C₅₀H₅₀F₆N₂P₂Rh*ClO₄
• Molecular Weight: 1057.25
• Mol file: 115564-83-5.mol

Synonyms:

Chemical Property of dihydride(1,4-biscyclohexyl-diaza-1,3-butadiene)bis(4-fluor-tristriphenylphosphine)rhodium(III) perchlorate

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of dihydride(1,4-biscyclohexyl-diaza-1,3-butadiene)bis(4-fluor-tristriphenylphosphine)rhodium(III) perchlorate

There total 1 articles about dihydride(1,4-biscyclohexyl-diaza-1,3-butadiene)bis(4-fluor-tristriphenylphosphine)rhodium(III) perchlorate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

{Rh(1,4-biscyclohexyl-diaza-1,3-butadiene)(COD)}(1+) (115564-89-1) + sodium perchlorate + P(p-C6H4F)3 (18437-78-0) → dihydride(1,4-biscyclohexyl-diaza-1,3-butadiene)bis(4-fluor-tristriphenylphosphine)rhodium(III) perchlorate (115564-83-5)

Guidance literature:

With hydrogen; In methanol; diethyl ether; water; addn. of phosphine in diethyl ether to a soln. of Rh-compd. in methanol, hydrogen bubbled through for 3 h, addn. of an aqueous soln. of NaClO4; partial evapn. of solvent, recrystn. (methanol-ethyl ether);

DOI:10.1016/S0020-1693(00)82013-7

Reference yield: 50.0%

dihydride(1,4-biscyclohexyl-diaza-1,3-butadiene)bis(4-fluor-tristriphenylphosphine)rhodium(III) perchlorate (115564-83-5) → {Rh(DMAD)2(c-Hex-DAB)(P(C6H4-p-F)3)}ClO4

Guidance literature:

With MeOOCCCCOOMe; In dichloromethane; byproducts: H2; N2 atmosphere, refluxing (3 h); crystn. on addn. of ethyl ether, recrystn. (CH2Cl2/MeOH/petroleum ether); elem. anal.;

DOI:10.1016/0022-328X(80)83010-5

Reference yield: 50.0%

dihydride(1,4-biscyclohexyl-diaza-1,3-butadiene)bis(4-fluor-tristriphenylphosphine)rhodium(III) perchlorate (115564-83-5) → {Rh(DMAD)(c-Hex-DAB)(P(C6H4-p-F)3)2}ClO4

Guidance literature:

With MeOOCCCCOOMe; In dichloromethane; byproducts: H2; N2 atmosphere, treatment at room temp.; crystn. on addn. of ethyl ether, recrystn. (CH2Cl2/MeOH/petroleum ether); elem. anal.;

DOI:10.1016/0022-328X(80)83010-5

upstream raw materials:

{Rh(1,4-biscyclohexyl-diaza-1,3-butadiene)(COD)}⁽¹⁺⁾

P(p-C₆H₄F)3