Li⁽¹⁺⁾*BC₆H₅H₃^(1-)*(CH₃)2NCH₂CH₂N(CH₃)2 = Li[BH₃C₆H₅]*(CH₃)2NCH₂CH₂N(CH₃)2

Base Information

• Chemical Name: Li⁽¹⁺⁾*BC₆H₅H₃^(1-)*(CH₃)2NCH₂CH₂N(CH₃)2 = Li[BH₃C₆H₅]*(CH₃)2NCH₂CH₂N(CH₃)2
• CAS No.: 84280-44-4
• Molecular Formula: C₆H₈B*C₆H₁₆N₂*Li
• Molecular Weight: 214.088
• Mol file: 84280-44-4.mol

Synonyms:

Chemical Property of Li⁽¹⁺⁾*BC₆H₅H₃^(1-)*(CH₃)2NCH₂CH₂N(CH₃)2 = Li[BH₃C₆H₅]*(CH₃)2NCH₂CH₂N(CH₃)2

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of Li⁽¹⁺⁾*BC₆H₅H₃^(1-)*(CH₃)2NCH₂CH₂N(CH₃)2 = Li[BH₃C₆H₅]*(CH₃)2NCH₂CH₂N(CH₃)2

There total 2 articles about Li⁽¹⁺⁾*BC₆H₅H₃^(1-)*(CH₃)2NCH₂CH₂N(CH₃)2 = Li[BH₃C₆H₅]*(CH₃)2NCH₂CH₂N(CH₃)2 which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 93.0%

lithium (trihydro)phenylborate + N,N,N,N,-tetramethylethylenediamine (110-18-9) → Li(1+)*BC6H5H3(1-)*(CH3)2NCH2CH2N(CH3)2 = Li[BH3C6H5]*(CH3)2NCH2CH2N(CH3)2 (84280-44-4)

Guidance literature:

In pentane; (N2); mole ratio TMED : Li(BPhH3) = 1 : 1; TMED added to 0.5 M soln. ofLi(BPhH3) in n-pentane at 25 °C; an exothermic react. set in andthe addn. compd. crystd. from the react. mixt. at 25 °C; (N2); centrifugation; supernatant liquid removed; crystalline solid washed (pentane) and dried (25 °C, 12 mmHg);

DOI:10.1021/om00083a022

Reference yield: 35.0%

Li(tetramethylethylenediamine)BH3(benzyl) + trimethylamine borane (1231953-83-5) → Li(1+)*BC6H5H3(1-)*(CH3)2NCH2CH2N(CH3)2 = Li[BH3C6H5]*(CH3)2NCH2CH2N(CH3)2 (84280-44-4)

Guidance literature:

In hexane; benzene; under dry N2, soln. of PhLi-TMEDA in hexane and benzene heated to reflux, Me3N-BH3 added, mixt. refluxed for 12 h, allowed to stand for 3 d; filtered, washed with cold pentane, elem. anal.;

upstream raw materials:

trimethylamine borane

N,N,N,N,-tetramethylethylenediamine