((C₆H₅)2PN(C₆H₁₁)P(C₆H₅)2)CrCl₃(NCCH₃)

Base Information

• Chemical Name: ((C₆H₅)2PN(C₆H₁₁)P(C₆H₅)2)CrCl₃(NCCH₃)
• CAS No.: 1048374-64-6
• Molecular Formula: C₃₂H₃₄Cl₃CrN₂P₂
• Molecular Weight: 666.938
• Mol file: 1048374-64-6.mol

Synonyms:

Chemical Property of ((C₆H₅)2PN(C₆H₁₁)P(C₆H₅)2)CrCl₃(NCCH₃)

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of ((C₆H₅)2PN(C₆H₁₁)P(C₆H₅)2)CrCl₃(NCCH₃)

There total 1 articles about ((C₆H₅)2PN(C₆H₁₁)P(C₆H₅)2)CrCl₃(NCCH₃) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 48.0%

([Ph2PN(C6H11)PPh2]CrCl2(μ2-Cl))2 + acetonitrile (75-05-8,26809-02-9) → ((C6H5)2PN(C6H11)P(C6H5)2)CrCl3(NCCH3) (1048374-64-6)

Guidance literature:

In acetonitrile; under N2 or Ar; MeCN added to solid Cr complex; kept at -30°C for1 d; mother liquor removed; crystals washed with hexane; dried under vac.; elem. anal.;

DOI:10.1021/om800353a

Reference yield: 96.0%

((C6H5)2PN(C6H11)P(C6H5)2)CrCl3(NCCH3) (1048374-64-6) + water (7732-18-5) → ((C6H5)2P(O)C(CH3)(NH2)P(C6H5)2O)CrCl3*H2O

Guidance literature:

In acetonitrile; under N2; Cr complex dissolved in MeCN; H2O added; stirred for 7 d; stored overnight; mother liquor decanted; solid dried under vac.; elem. anal.;

DOI:10.1021/om800353a

upstream raw materials:

acetonitrile