Me₃Al(C((N-mesityl)N(CHCH)N(CHCH₂NH-t-Bu)))

Base Information

• Chemical Name: Me₃Al(C((N-mesityl)N(CHCH)N(CHCH₂NH-t-Bu)))
• CAS No.: 1113064-10-0
• Molecular Formula: C₂₁H₃₆AlN₃
• Molecular Weight: 357.518
• Mol file: 1113064-10-0.mol

Synonyms:

Chemical Property of Me₃Al(C((N-mesityl)N(CHCH)N(CHCH₂NH-t-Bu)))

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of Me₃Al(C((N-mesityl)N(CHCH)N(CHCH₂NH-t-Bu)))

There total 1 articles about Me₃Al(C((N-mesityl)N(CHCH)N(CHCH₂NH-t-Bu))) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 75.0%

[CN(mesityl)CHCHN(C2H4NH-t-Bu)]LiBr(THF) + trimethylaluminum (75-24-1) → Me3Al(C((N-mesityl)N(CHCH)N(CHCH2NH-t-Bu))) (1113064-10-0)

Guidance literature:

In tetrahydrofuran; toluene; (N2); Schlenk technique; soln. of AlMe3 in toluene was added to soln. ofLi compd. in THF at room temp.; stirred for 12 h; evapd. (vac.); extd. (toluene); filtered; filtrate dried (vac.); recrystd. (ether/hexane, 1/1, -30°C); elem. anal.;

DOI:10.1021/om800917j

Reference yield: 90.0%

Me3Al(C((N-mesityl)N(CHCH)N(CHCH2NH-t-Bu))) (1113064-10-0) → Me2Al(κ2-C,N-C((N-mesityl)N(CHCH)N(CHCH2N-t-Bu)))

Guidance literature:

In toluene; (N2); Schlenk technique; soln. of Al compd. in toluene was heated at 110°C for 1 d; evapd. (vac.); recrystd. (ether/hexane, 50/50, -20°C); elem. anal.;

DOI:10.1021/om200878e

Reference yield: 70.0%

Me3Al(C((N-mesityl)N(CHCH)N(CHCH2NH-t-Bu))) (1113064-10-0) + p-Tolylisocyanate (622-58-2,374675-64-6) → Me3Al(OC(=NC6H4Me)C((N-mesityl)N(CHCH)N(CHCH2NH-t-Bu))) (1354047-44-1)

Guidance literature:

In tetrahydrofuran; (N2); Schlenk technique; isocyanate was added to soln. of Al compd. in THF at -20°C; stirred for 2 h; dried (vac.); washed (hexane); recrystd. (ether, -20°C);

DOI:10.1021/om200878e

upstream raw materials:

trimethylaluminum

Downstream raw materials:

Me₃Al(OC(=NC₆H₄Me)C((N-mesityl)N(CHCH)N(CHCH₂NH-t-Bu)))

Me₃Al(N(Cy)C(NCy)C((N-mesityl)N(CHCH)N(CHCH₂NH-t-Bu)))