tris(1,1,1,5,5,5-hexafluoropentane-2,4-dionata)diaquayttrium

Base Information

• Chemical Name: tris(1,1,1,5,5,5-hexafluoropentane-2,4-dionata)diaquayttrium
• CAS No.: 210057-51-5
• Molecular Formula: C₁₅H₇F₁₈O₈Y
• Molecular Weight: 746.093
• Mol file: 210057-51-5.mol

Synonyms:

Chemical Property of tris(1,1,1,5,5,5-hexafluoropentane-2,4-dionata)diaquayttrium

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of tris(1,1,1,5,5,5-hexafluoropentane-2,4-dionata)diaquayttrium

There total 2 articles about tris(1,1,1,5,5,5-hexafluoropentane-2,4-dionata)diaquayttrium which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 75.0%

1,1,1,5,5,5-hexafluoroacetylacetone (1522-22-1) + yttrium(III) chloride hexahydrate → tris(1,1,1,5,5,5-hexafluoropentane-2,4-dionata)diaquayttrium (210057-51-5,33751-70-1,20860-73-5)

Guidance literature:

1,1,1,5,5,5-hexafluoroacetylacetone; In water; for 0.5h;

yttrium(III) chloride hexahydrate; With ammonia; In diethyl ether; water;

DOI:10.1021/ic500779y

Reference yield:

yttrium(III) hexafluoroacetylacetonate + bis(acetylacetonate)copper(II) → tris(1,1,1,5,5,5-hexafluoropentane-2,4-dionata)diaquayttrium (210057-51-5,33751-70-1,20860-73-5) + yttrium(III)hexafluoroacetylacetonate dihydrate*copper(II)acetylacetonate (210057-52-6)

Guidance literature:

In ethanol; byproducts: Cu((CH3CO)2CH)2; mixt. in 96% C2H5OH boiled for 1 h, refluxed at reduced pressure; crystd. in air; elem. anal., single crystal XRD, TGA;

Reference yield:

tris(1,1,1,5,5,5-hexafluoropentane-2,4-dionata)diaquayttrium (210057-51-5,33751-70-1,20860-73-5) + C68H68O12P4*C15H14N4O*ClH → C30H17F18N4O7Y*C68H68O12P4*H(1+)*Cl(1-)

Guidance literature:

In dichloromethane; at 20 ℃; for 1h;

DOI:10.1002/ejic.201402117

upstream raw materials:

1,1,1,5,5,5-hexafluoroacetylacetone