[Ru(η5-pentamethylcyclopentadienyl)(H)2(P(i-Pr)3)(SiPh2)]B(C6F5)4

Base Information

Chemical Name:[Ru(η5-pentamethylcyclopentadienyl)(H)2(P(i-Pr)3)(SiPh2)]B(C6F5)4
CAS No.:1335244-46-6
Molecular Formula:C₂₄BF₂₀*C₃₁H₄₈PRuSi
Molecular Weight:1259.89
Hs Code.:

Synonyms:

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Chemical Property of [Ru(η5-pentamethylcyclopentadienyl)(H)2(P(i-Pr)3)(SiPh2)]B(C6F5)4

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Technology Process of [Ru(η5-pentamethylcyclopentadienyl)(H)2(P(i-Pr)3)(SiPh2)]B(C6F5)4

There total 1 articles about [Ru(η5-pentamethylcyclopentadienyl)(H)2(P(i-Pr)3)(SiPh2)]B(C6F5)4 which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 57.0%

: [Et₃Si*toluene][B(C₆F₅)4]

: 1335244-36-4
[Ru(η5-pentamethylcyclopentadienyl)(P(i-Pr)3)(SiPh2(OTf))(H)2]

: 1335244-46-6
[Ru(η5-pentamethylcyclopentadienyl)(H)2(P(i-Pr)3)(SiPh2)]B(C6F5)4

Guidance literature:: In fluorobenzene; byproducts: Et3SiOTf; (N2); using Schlenk techniques; addn. of soln. of (Et3Si*toluene)(B(C6F5)4) in C6H5F to soln. of (Ru(η5-pentamethylcyclopentadienyl)(H)2(P(i-Pr)3)(SiPh2OTf)) in C6H5F, stirring for 5 min at room temp.; addn. of pentane, cooling to -30°C for 1 h, decanting, drying under vac. for 1 h; elem. anal.;
DOI:10.1021/om200795x

Reference yield: 93.0%

: 1335244-46-6
[Ru(η5-pentamethylcyclopentadienyl)(H)2(P(i-Pr)3)(SiPh2)]B(C6F5)4

: 55-21-0,27208-38-4
benzamide

: 1384170-17-5
[(η5-C5Me5)(P(i-Pr)3)Ru(SiPh2(PhCONH2))][B(C6F5)4]

Guidance literature:: In fluorobenzene; (N2); std. Schlenk technique; soln. of benzamide in C6H5F was added to soln. of Ru complex in C6H5F; dried (vac.); washed (hexane); dried (vac.); elem. anal.;
DOI:10.1021/om300390n

Reference yield: 89.0%

: 1335244-46-6
[Ru(η5-pentamethylcyclopentadienyl)(H)2(P(i-Pr)3)(SiPh2)]B(C6F5)4

: 146374-27-8
S-tert-butylsulfinimide

: 1384170-23-3
[(η5-C5Me5)(P(i-Pr)3)Ru(SiPh2(t-BuSONH2))][B(C6F5)4]

Guidance literature:: In fluorobenzene; (N2); std. Schlenk technique; soln. of amide in C6H5F was added to soln.of Ru complex in C6H5F; stirred for 10 min; dried (vac.); washed (hexane); dried (vac.); elem. anal.;
DOI:10.1021/om300390n