N-Benzoylsulfonyl-dithiocarbaminsaeure

Base Information

• Chemical Name: N-Benzoylsulfonyl-dithiocarbaminsaeure
• CAS No.: 52429-54-6
• Molecular Formula: C₇H₇NO₂S₃
• Molecular Weight: 233.336
• Mol file: 52429-54-6.mol

Synonyms:

Chemical Property of N-Benzoylsulfonyl-dithiocarbaminsaeure

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of N-Benzoylsulfonyl-dithiocarbaminsaeure

There total 1 articles about N-Benzoylsulfonyl-dithiocarbaminsaeure which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

carbon disulfide (75-15-0,12122-00-8) + benzenesulfonamide (98-10-2) → N-Benzoylsulfonyl-dithiocarbaminsaeure (52429-54-6)

Guidance literature:

With potassium hydroxide; In N,N-dimethyl-formamide;

DOI:10.1002/ardp.19662990212

Reference yield:

N-Benzoylsulfonyl-dithiocarbaminsaeure (52429-54-6) → ethyl 2-cyano-3-methylthio-3-phenylsulfonylaminoacrylate

Guidance literature:

Multi-step reaction with 2 steps

1: aq. NaOH / dimethylformamide / 1 h

2: 70 percent / K₂CO₃ / dimethylsulfoxide / 3 h / Ambient temperature

With sodium hydroxide; potassium carbonate; In dimethyl sulfoxide; N,N-dimethyl-formamide;

Reference yield:

N-Benzoylsulfonyl-dithiocarbaminsaeure (52429-54-6) → ethyl 5-amino-1-methyl-3-phenylsulfonylaminopyrazole-4-carboxylate

Guidance literature:

Multi-step reaction with 3 steps

1: aq. NaOH / dimethylformamide / 1 h

2: 70 percent / K₂CO₃ / dimethylsulfoxide / 3 h / Ambient temperature

3: 13 percent / ethanol / 1 h / Heating

With sodium hydroxide; potassium carbonate; In ethanol; dimethyl sulfoxide; N,N-dimethyl-formamide;

upstream raw materials:

carbon disulfide

benzenesulfonamide

Downstream raw materials:

N-bis-(methylsulfanylmethylene)benzenesulfonamide

Refernces

• 1、 Hartke. "Description of sulfonyl isothiocyanates". . p. 174 - 178. Retrieved 2007/10/09.