[Sm(μ-NHC6H3iPr-2,6)(NHC6H3(i-Pr)2-2,6)2]2

Base Information

Chemical Name:[Sm(μ-NHC6H3iPr-2,6)(NHC6H3(i-Pr)2-2,6)2]2
CAS No.:475661-97-3
Molecular Formula:C₇₂H₁₀₈N₆Sm₂
Molecular Weight:1358.41
Hs Code.:

Synonyms:

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of [Sm(μ-NHC6H3iPr-2,6)(NHC6H3(i-Pr)2-2,6)2]2

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Technology Process of [Sm(μ-NHC6H3iPr-2,6)(NHC6H3(i-Pr)2-2,6)2]2

There total 1 articles about [Sm(μ-NHC6H3iPr-2,6)(NHC6H3(i-Pr)2-2,6)2]2 which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 78.0%

: tris(bis(trimethylsilyl)amido)samarium(III)

: 24544-04-5
2,6-diisopropylbenzenamine

: 475661-97-3
[Sm(μ-NHC6H3iPr-2,6)(NHC6H3(i-Pr)2-2,6)2]2

Guidance literature:: In toluene; byproducts: HN(SiMe3)2; a toluene-soln. of aniline was added to a soln. of complex in toluene, the mixt. was stirred at room temp. for 15 min then heated to reflux for 15 min, cooled (Ar); solvent was removed under vac., ppt. was washed with hexane, filtered, pumped to dryness; elem. anal.;
DOI:10.1021/om0206960

Reference yield:

: 475661-97-3
[Sm(μ-NHC6H3iPr-2,6)(NHC6H3(i-Pr)2-2,6)2]2

: 75-24-1
trimethylaluminum

: [(2,6-diisopropylphenyl)HNAlMe₂]2

: [(μ-NC6H3(i-Pr)2-2,6)Sm(μ-NHC6H3iPr-2,6)(μ-Me)AlMe2]2

Guidance literature:: In hexane; toluene; a soln. of AlMe3 in hexane was added to toluene slurry of complex (Ar); solvent was removed under vac., hexane was added with stirring, the mixt. was pumped dry, the procedure was repeated, hexane was added, filtered, concd., allowed to slow evapd., solid was washed with cold hexane, pumped; elem. anal.;
DOI:10.1021/om0206960