C₃₃H₅₁N₅O₁₈

Base Information

• Chemical Name: C₃₃H₅₁N₅O₁₈
• CAS No.: 1426150-68-6
• Molecular Formula: C₃₃H₅₁N₅O₁₈
• Molecular Weight: 805.791
• Mol file: 1426150-68-6.mol

Synonyms:

Chemical Property of C₃₃H₅₁N₅O₁₈

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of C₃₃H₅₁N₅O₁₈

There total 9 articles about C₃₃H₅₁N₅O₁₈ which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

C34H44F3NO22 → C33H51N5O18 (1426150-68-6)

Guidance literature:

Multi-step reaction with 3 steps

1.1: titanium(IV) bromide / dichloromethane / 3 h / 20 °C

2.1: silver trifluoromethanesulfonate; tetramethylurea / dichloromethane / 20 h / 20 °C / Molecular sieve

3.1: sodium methylate; methanol / 1 h

3.2: 16 h

With methanol; sodium methylate; silver trifluoromethanesulfonate; titanium(IV) bromide; tetramethylurea; In dichloromethane;

DOI:10.1055/s-0032-1317961

Reference yield:

Acetic acid (2R,3S,4R,5R,6R)-3-acetoxy-2-acetoxymethyl-5-acetylamino-6-chloro-tetrahydro-pyran-4-yl ester (3068-34-6) → C33H51N5O18 (1426150-68-6)

Guidance literature:

Multi-step reaction with 8 steps

1.1: 1,2-dichloro-ethane

2.1: sodium azide / dimethyl sulfoxide / 80 °C

3.1: sodium methylate; methanol

4.1: toluene-4-sulfonic acid / acetonitrile

5.1: pyridine

6.1: sodium cyanoborohydride; methanesulfonic acid / tetrahydrofuran

7.1: silver trifluoromethanesulfonate; tetramethylurea / dichloromethane / 20 h / 20 °C / Molecular sieve

8.1: sodium methylate; methanol / 1 h

8.2: 16 h

With pyridine; methanol; sodium azide; methanesulfonic acid; sodium methylate; silver trifluoromethanesulfonate; sodium cyanoborohydride; toluene-4-sulfonic acid; tetramethylurea; In tetrahydrofuran; dichloromethane; dimethyl sulfoxide; 1,2-dichloro-ethane; acetonitrile;

DOI:10.1055/s-0032-1317961

Reference yield:

3-chloropropyl 3,4,6-tri-O-acetyl-2-deoxy-2-acetamido-β-D-glucopyranoside (1202384-52-8) → C33H51N5O18 (1426150-68-6)

Guidance literature:

Multi-step reaction with 7 steps

1.1: sodium azide / dimethyl sulfoxide / 80 °C

2.1: sodium methylate; methanol

3.1: toluene-4-sulfonic acid / acetonitrile

4.1: pyridine

5.1: sodium cyanoborohydride; methanesulfonic acid / tetrahydrofuran

6.1: silver trifluoromethanesulfonate; tetramethylurea / dichloromethane / 20 h / 20 °C / Molecular sieve

7.1: sodium methylate; methanol / 1 h

7.2: 16 h

With pyridine; methanol; sodium azide; methanesulfonic acid; sodium methylate; silver trifluoromethanesulfonate; sodium cyanoborohydride; toluene-4-sulfonic acid; tetramethylurea; In tetrahydrofuran; dichloromethane; dimethyl sulfoxide; acetonitrile;

DOI:10.1055/s-0032-1317961

upstream raw materials:

C₃₂H₄₁BrF₃NO₂₀

Acetic acid (2R,3S,4R,5R,6R)-3-acetoxy-2-acetoxymethyl-5-acetylamino-6-chloro-tetrahydro-pyran-4-yl ester

3-chloropropyl 3,4,6-tri-O-acetyl-2-deoxy-2-acetamido-β-D-glucopyranoside

3-azidopropyl 2-acetamido-3,4,6-tri-O-acetyl-2-deoxy-β-D-glucopyranoside