2,2-trans-tetrakis(μ-2-anilinopyridinato)dirhodium

Base Information

Chemical Name:2,2-trans-tetrakis(μ-2-anilinopyridinato)dirhodium
CAS No.:99243-16-0
Molecular Formula:C₄₄H₃₆N₈Rh₂
Molecular Weight:882.634
Hs Code.:

Synonyms:

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Chemical Property of 2,2-trans-tetrakis(μ-2-anilinopyridinato)dirhodium

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Technology Process of 2,2-trans-tetrakis(μ-2-anilinopyridinato)dirhodium

There total 2 articles about 2,2-trans-tetrakis(μ-2-anilinopyridinato)dirhodium which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 52.0%

: rhodium(III) chloride trihydrate

: 6631-37-4
2-(phenylamino)pyridine

: 99243-16-0
2,2-trans-tetrakis(μ-2-anilinopyridinato)dirhodium

Guidance literature:: With sodium; In ethanol; addn. of sodium to 2-anilinopyridine in ethanol; stirring for 15 min; addn. of chloride; refluxing mixture for 3 h under N2; pptn.; recrystallization from methanol; extraction with minimum volume of CH2Cl2; addn. of cold ethanol; pptn.; drying in vacuum at ambient temp.; elem. anal.;
DOI:10.1016/S0277-5387(00)84567-2

Reference yield: 22.0%

: rhodium(III) chloride trihydrate

: 130468-98-3
sodium 2-(phenylamino)pyridinate

: 99243-16-0
2,2-trans-tetrakis(μ-2-anilinopyridinato)dirhodium

Guidance literature:: In ethanol; Rh salt was refluxed with excess of sodium salt in EtOH (method described by Tocher, D. A., Tocher, J. L., Inorg. Chim. Acta 1985, 104, L 15); recrystn. from CH2Cl2/hexane;
DOI:10.1021/ic00306a012

Reference yield:

: 99243-16-0
2,2-trans-tetrakis(μ-2-anilinopyridinato)dirhodium

: 119072-84-3
Rh₂(C₅H₄NNC₆H₅)4CO

Guidance literature:: With CO; In dichloromethane; soln. of Rh complex under pressure of 1 atm CO; monitored by cyclovoltammetry;
DOI:10.1021/ic00306a012