[(η5-C5H5)Ti(OC6H3(t-Bu)2-2,6)Me2]

Base Information

• Chemical Name: [(η5-C5H5)Ti(OC6H3(t-Bu)2-2,6)Me2]
• CAS No.: 874291-09-5
• Molecular Formula: C₂₁H₃₂OTi
• Molecular Weight: 348.364
• Mol file: 874291-09-5.mol

Synonyms:

Chemical Property of [(η5-C5H5)Ti(OC6H3(t-Bu)2-2,6)Me2]

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of [(η5-C5H5)Ti(OC6H3(t-Bu)2-2,6)Me2]

There total 1 articles about [(η5-C5H5)Ti(OC6H3(t-Bu)2-2,6)Me2] which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 91.0%

(C5H5)Ti(Cl)2(OC6H3(C(CH3)3)2) (172659-92-6) + methyllithium (917-54-4) → [(η5-C5H5)Ti(OC6H3(t-Bu)2-2,6)Me2] (874291-09-5)

Guidance literature:

In benzene; byproducts: LiCl; (N2 atm.; Schlenk) LiCH3 in (C2H5)2O was added was a chilled soln. (10°C) of complex in benzene, the mixt. was slowly warmed to room temp. in 30 min, stirred for 2 h; the solvent was removed under vac., hexane was added, the suspn. was filtered, evacuated to dryness; elem. anal.;

DOI:10.1021/om0507272

Reference yield:

[(η5-C5H5)Ti(OC6H3(t-Bu)2-2,6)Me2] (874291-09-5) + tris(pentafluorophenyl)borate (1109-15-5) → [(η5-C5H5)Ti(OC6HPh4-2,3,5,6)Me][MeB(C6F5)3] (874291-15-3,695229-58-4)

Guidance literature:

In ⁽²⁾H₈-toluene; (N2 atm.; Schlenk) an NMR tube was charged with complex and toluene-d8, a soln. of B(C6F5)3 in toluene-d8 was added at -25°C; not sepd., detected by NMR spectra;

DOI:10.1021/om0507272

Reference yield:

[(η5-C5H5)Ti(OC6H3(t-Bu)2-2,6)Me2] (874291-09-5) + tris(pentafluorophenyl)borate (1109-15-5) → [(η5-C5H5)Ti(OC6H3(t-Bu)2-2,6)Me][MeB(C6F5)3] (874291-14-2)

Guidance literature:

In ⁽²⁾H₈-toluene; (N2 atm.; Schlenk) an NMR tube was charged with complex and toluene-d8, a soln. of B(C6F5)3 in toluene-d8 was added at -25°C; not sepd., detected by NMR spectra;

DOI:10.1021/om0507272

upstream raw materials:

(C₅H₅)Ti(Cl)2(OC₆H₃(C(CH₃)3)2)

methyllithium

Downstream raw materials:

[(η5-C5H5)Ti(OC6HPh4-2,3,5,6)Me][MeB(C6F5)3]

[(η5-C5H5)Ti(OC6H3(t-Bu)2-2,6)Me][MeB(C6F5)3]