P(C₆H₅)4⁽¹⁺⁾*Ag(CF₃)3(CN)^(1-)=[P(C₆H₅)4][Ag(CF₃)3(CN)]

Base Information

Chemical Name:P(C₆H₅)4⁽¹⁺⁾*Ag(CF₃)3(CN)^(1-)=[P(C₆H₅)4][Ag(CF₃)3(CN)]
CAS No.:188290-04-2
Molecular Formula:C₄AgF₉N*C₂₄H₂₀P
Molecular Weight:680.301
Hs Code.:

P(C<sub>6</sub>H<sub>5</sub>)4<sup>(1+)</sup>*Ag(CF<sub>3</sub>)3(CN)<sup>(1-)</sup>=[P(C<sub>6</sub>H<sub>5</sub>)4][Ag(CF<sub>3</sub>)3(CN)]

Synonyms:

Suppliers and Price of P(C₆H₅)4⁽¹⁺⁾*Ag(CF₃)3(CN)^(1-)=[P(C₆H₅)4][Ag(CF₃)3(CN)]

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 0 raw suppliers

Chemical Property of P(C₆H₅)4⁽¹⁺⁾*Ag(CF₃)3(CN)^(1-)=[P(C₆H₅)4][Ag(CF₃)3(CN)]

Chemical Property:

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Technology Process of P(C₆H₅)4⁽¹⁺⁾*Ag(CF₃)3(CN)^(1-)=[P(C₆H₅)4][Ag(CF₃)3(CN)]

There total 4 articles about P(C₆H₅)4⁽¹⁺⁾*Ag(CF₃)3(CN)^(1-)=[P(C₆H₅)4][Ag(CF₃)3(CN)] which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 25.0%

: 188290-03-1
Ag(CF₃)3(CN)^(1-)

: 2001-45-8
tetraphenyl phosphonium chloride

: 188363-78-2,188289-74-9
[PPh₄][cis-Ag(CF₃)2(CN)2]

: 188289-74-9,188363-78-2
[P(C₆H₄)4][trans-Ag(CF₃)2(CN)2]

: 188290-04-2
P(C₆H₅)4⁽¹⁺⁾*Ag(CF₃)3(CN)^(1-)=[P(C₆H₅)4][Ag(CF₃)3(CN)]

Guidance literature:: With Br₂; In diethylene glycol dimethyl ether; N,N-dimethyl-formamide; inert atmosphere; addn. of Br2 (in diglyme) to Ag-complex (in DMF) at -50°C, warming to room temp., PPh4Cl addn., stirring for 20 min; CHCl3 addn., washing (water), drying (MgSO4), solvent removal (vac.), repeated dissoln. in CHCl3 and pptn. on Et2O addn. (NMR monitoring), recrystn. (Et2O diffusion into CHCl3 soln.); elem. anal.; cis-isomer from mother liquor;
DOI:10.1021/ic9610445

Reference yield:

: 2001-45-8
tetraphenyl phosphonium chloride

: 188290-04-2
P(C₆H₅)4⁽¹⁺⁾*Ag(CF₃)3(CN)^(1-)=[P(C₆H₅)4][Ag(CF₃)3(CN)]

Guidance literature:: Multi-step reaction with 2 steps

1: Br₂ / diethylene glycol dimethyl ether; N,N-dimethyl-formamide

2: Br₂ / N,N-dimethyl-formamide

With Br₂; In diethylene glycol dimethyl ether; N,N-dimethyl-formamide;
DOI:10.1021/ic9610445

Reference yield:

: potassium cyanide

: 188289-74-9,188363-78-2
[P(C₆H₄)4][trans-Ag(CF₃)2(CN)2]

: silver nitrate

: 188290-04-2
P(C₆H₅)4⁽¹⁺⁾*Ag(CF₃)3(CN)^(1-)=[P(C₆H₅)4][Ag(CF₃)3(CN)]

: P(C₆H₅)4⁽¹⁺⁾*Ag(CF₃)4^(1-)=[P(C₆H₅)4][Ag(CF₃)4]

Guidance literature:: With Br₂; In N,N-dimethyl-formamide; byproducts: AgBr; inert atmosphere; treatment of Ag-complex with Br2 at -10°C, AgNO3 addn. (-30°C), stirring for 10 min, centrifugation off of AgBr (-40°C), addn. of excess KCN, warming to room temp. over 2 h; CHCl3 addn., washing (water), drying (MgSO4), evapn. (vac.), dissoln. inCHCl3, Et2O addn., filtration, evapn.; product mixt. not sepd.;
DOI:10.1021/ic9610445